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Durable Superhydrophobic and Antireflective Surfaces by Trimethylsilanized Silica Nanoparticles-Based Sol−Gel Processing
Open accessAbstract
We present a robust and cost-effective coating method to fabricate long-term durable superhydrophobic andsimultaneouslyantireflective surfaces by a double-layer coating comprising trimethylsiloxane (TMS) surface-functionalized silica nanoparticles partially embedded into an organosilica binder matrix produced through a sol-gel process. A dense and homogeneous organosilica gel layer was first coated onto a glass substrate, and then, a trimethylsilanized nanospheres-based superhydrophobic layer was deposited onto it. After thermal curing, the two layers turned into a monolithic film, and the hydrophobic nanoparticles were permanently fixed to the glass substrate. Such treated surfaces showed a tremendous water repellency (contact angle = 168 degrees ) and stable self-cleaning effect during 2000 h of outdoor exposure. Besides this, nanotextured topology generated by the self-assembled nanoparticles-based top layer produced a fair antireflection effect consisting of more than a 3% increase in optical transmittance.
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Cites
Wettability of porous surfaces
Cassie, A. B. D., & Baxter, S. (1944) · Transactions of the Faraday Society · doi:10.1039/tf9444000546 · Cited by 13,807
Cited by
Applications of Bio‐Inspired Special Wettable Surfaces
Yao, X., Song, Y., & Jiang, L. (2011) · Advanced Materials · doi:10.1002/adma.201002689 · Cited by 1,073
Robust superhydrophobicity: mechanisms and strategies
Zhang, W., Wang, D., Sun, Z., Song, J., & Deng, X. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00751j · Cited by 686
Nanocomposite Coatings: Preparation, Characterization, Properties, and Applications
Nguyen-Tri, P., Nguyen, T. A., Carriere, P., & Ngo Xuan, C. (2018) · International Journal of Corrosion · doi:10.1155/2018/4749501 · Cited by 267
Metadata
- Authors
- Manca, M., Cannavale, A., De Marco, L., Aricò, A. S., Cingolani, R., & Gigli, G.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-04-29
- Volume
- 25
- Issue
- 11
- Pages
- 6357-6362
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2035501131
- Cited by
- 339
- References
- 1
- FWCI
- 8.18
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Durable Superhydrophobic and Antireflective Surfaces by Trimethylsilanized Silica Nanoparticles-Based Sol−Gel Processing. https://app.cochat.ai/papers/10.1021/la804166t
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- Manca, M., Cannavale, A., De Marco, L., Aricò, A. S., Cingolani, R., & Gigli, G. (2009). Durable Superhydrophobic and Antireflective Surfaces by Trimethylsilanized Silica Nanoparticles-Based Sol−Gel Processing. Langmuir. https://doi.org/10.1021/la804166t
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