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Preparation, Characterization, and Surface Modification of Silver Particles
Abstract
Colloidal silver has been formed either by irradiation with 253.7 nm light or by chemical reduction of AgClO 4 in the presence of protective agents such as poly(vinylpyrrolidone), carboxy methyl cellulose, and gelatin. The particles were characterized by their absorption maximum and transmission electron micrographs. Peptization effect was observed in the presence of photosensitive benzophenone. Surface modification studies of silver particles in the presence of various complexing agents, viz., N -(hydoxyethyl)ethylenediaminetriacetic acid, iminodiacetic acid, nitrilotriacetic acid, 2-mercaptobenzimidazole, benzotriazole, 5-aminotetrazole, imidazole, and sanazole were carried out and it was shown that the reactivity of silver particles increases in their presence. However, in the presence of stabilizers, due to competitve reactions, partial recovery of the surface plasmon absorption band was observed. The Fermi potential of surface modified silver particles seems to lie in the range of −0.40 ± 0.05 V.
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Cites
Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
Mie, G. (1908) · Annalen der Physik · doi:10.1002/andp.19083300302 · Cited by 11,537
Cited by
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Iravani, S. (2014) · International Scholarly Research Notices · doi:10.1155/2014/359316 · Cited by 494
Preparation of colloidal silver nanoparticles by chemical reduction method
Song, K. C., Lee, S. M., Park, T. S., & Lee, B. S. (2009) · Korean Journal of Chemical Engineering · doi:10.1007/s11814-009-0024-y · Cited by 323
Aggregation and Dissolution of Silver Nanoparticles in Natural Surface Water
Li, X., & Lenhart, J. J. (2012) · Environmental Science & Technology · doi:10.1021/es204531y · Cited by 295
Metadata
- Authors
- Kapoor, S.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-02-13
- Volume
- 14
- Issue
- 5
- Pages
- 1021-1025
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1964415384
- Cited by
- 239
- References
- 1
- FWCI
- 4.75
- Type
- journal article
- Language
- en
- Open access
- closed
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