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Vibrational Spectroscopic Study of the Coordination of (2,2‘-Bipyridyl-4,4‘-dicarboxylic acid)ruthenium(II) Complexes to the Surface of Nanocrystalline Titania
Abstract
The coordination of photosensitizing Ru(II) dyes to a nanocrystalline titania film, as employed in the Grätzel solar cell, has been examined by vibrational spectroscopy. The major infrared bands of the adsorbed dyes have been assigned by comparison with spectra (IR and Raman) of the parent dye molecules, and suggest a bidentate chelate or bridging coordination to the TiO 2 surface via two carboxylate groups per dye molecule.
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Citations
Cited by
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Efficient Light Harvesting by Using Green Zn-Porphyrin-Sensitized Nanocrystalline TiO2 Films
Wang, Q., Campbell, W. M., Bonfantani, E. E., Jolley, K. W., Officer, D. L., Walsh, P. J., Gordon, K., Humphry-Baker, R., Nazeeruddin, M. K., & Grätzel, M. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp052877w · Cited by 438
Zhao, D., Chen, C., Wang, Y., Ma, W., Zhao, J., Rajh, T., & Zang, L. (2008) · Environmental Science & Technology · doi:10.1021/es071770e · Cited by 194
Metadata
- Authors
- Finnie, K. S., Bartlett, J. R., & Woolfrey, J. L.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-04-14
- Volume
- 14
- Issue
- 10
- Pages
- 2744-2749
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2066516787
- Cited by
- 330
- References
- 0
- FWCI
- 10.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Vibrational Spectroscopic Study of the Coordination of (2,2‘-Bipyridyl-4,4‘-dicarboxylic acid)ruthenium(II) Complexes to the Surface of Nanocrystalline Titania. https://app.cochat.ai/papers/10.1021/la971060u
- The paper
- Finnie, K. S., Bartlett, J. R., & Woolfrey, J. L. (1998). Vibrational Spectroscopic Study of the Coordination of (2,2‘-Bipyridyl-4,4‘-dicarboxylic acid)ruthenium(II) Complexes to the Surface of Nanocrystalline Titania. Langmuir. https://doi.org/10.1021/la971060u
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.