The DOI matches its Crossref record; 26 of the 26 references it cites were found in a registry or an index.
Controlled Method for Silica Coating of Silver Colloids. Influence of Coating on the Rate of Chemical Reactions
Abstract
The preparation and chemical reactivity of Ag@SiO 2 particles have been investigated using UV−vis spectroscopy, laser Doppler electrophoresis, and electron microscopy. The factors governing the deposition of silica onto silane-primed silver particles have been investigated and the deposition conditions (pH and reagent concentrations) optimized. It is demonstrated that the thin silica shells deposited from aqueous/ethanolic sodium silicate solutions are porous. Silver cores dissolve in alkaline cyanide solutions, with the rate depending on the shell thickness. Ag 2 S@SiO 2 can be prepared following exposure to sulfide ion, while silica-coated alloys of silver and gold can be prepared by reaction of Ag@SiO 2 with AuCl 4 - . The kinetics of these core reactions with solution reagents is governed by their rate of diffusion through the shell. A diffusion coefficient of 10 - 12 cm 2 s - 1 is estimated for cyanide ion diffusing through non-heat-treated silica shells.
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Synthesis of Nanosized Gold−Silica Core−Shell Particles
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Metadata
- Authors
- Ung, T., Liz-Marzán, L. M., & Mulvaney, P.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-06-10
- Volume
- 14
- Issue
- 14
- Pages
- 3740-3748
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2021087526
- Cited by
- 425
- References
- 26
- FWCI
- 5.03
- Type
- journal article
- Language
- en
- Open access
- closed
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