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Colloidal Dispersions of Gold Rods: Synthesis and Optical Properties
Abstract
Colloidal dispersions of rod-shaped gold particles are obtained by electrodeposition of gold in the nanopores of anodized alumina attached to a conductive support followed by dissolution of the alumina and release of the rods from the support. Coagulation is prevented by steric repulsion due to adsorption of poly(vinylpyrrolidone) on the gold surface. The synthesis method presented is suitable for the preparation of dispersions of nearly monodisperse colloidal gold rods with adjustable aspect ratio L / d in the range 1.8 < L / d < 49. The length, L, is tuned between 39 and 729 nm, and the diameter, d, is between 12 and 22 nm. The absorbance spectra of randomly oriented colloidal gold rods display a transverse and a longitudinal resonance contribution. With increasing aspect ratio, the transverse resonance shows a small shift to shorter wavelengths, while the longitudinal resonance shifts into the near-infrared regime. The positions of the absorbance maxima agree with the predictions of the Gans theory.
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Cites
Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
Mie, G. (1908) · Annalen der Physik · doi:10.1002/andp.19083300302 · Cited by 11,537
Cited by
Photophysical, Photochemical and Photocatalytic Aspects of Metal Nanoparticles
Kamat, P. V. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0209289 · Cited by 1,924
Gold Nanorods: From Synthesis and Properties to Biological and Biomedical Applications
Huang, X., Neretina, S., & El‐Sayed, M. A. (2009) · Advanced Materials · doi:10.1002/adma.200802789 · Cited by 1,921
Gold Nanomaterials at Work in Biomedicine
Yang, X., Yang, M., Pang, B., Vara, M., & Xia, Y. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00193 · Cited by 1,162
Rodlike cellulose microcrystals: Structure, properties and applications
de Souza Lima, M. M., & Borsali, R. (2004) · Macromolecular Rapid Communications · doi:10.1002/marc.200300268 · Cited by 894
Steric stabilization of a cellulose microcrystal suspension by poly(ethylene glycol) grafting
Araki, J., Wada, M., & Kuga, S. (2001) · Langmuir · doi:10.1021/la001070m · Cited by 720
Metadata
- Authors
- van der Zande, B. M. I., Böhmer, M. R., Fokkink, L. G. J., & Schönenberger, C.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-11-16
- Volume
- 16
- Issue
- 2
- Pages
- 451-458
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1984198171
- Cited by
- 298
- References
- 1
- FWCI
- 2.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- van der Zande, B. M. I., Böhmer, M. R., Fokkink, L. G. J., & Schönenberger, C. (2000). Colloidal Dispersions of Gold Rods: Synthesis and Optical Properties. Langmuir. https://doi.org/10.1021/la9900425
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.