The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Heating-Induced Evolution of Thiolate-Encapsulated Gold Nanoparticles: A Strategy for Size and Shape Manipulations
Abstract
A heating treatment strategy for inducing size and shape change of composite nanoparticles in solutions is described. The composite nanoparticles are ∼2 nm gold cores encapsulated with alkanethiolate monolayers. The development of abilities in size and shape controls constitutes the motivation of this work. We demonstrated a remarkable evolution of the preformed particles in solutions toward monodispersed larger core sizes with well-defined and highly faceted morphologies. The particles thus evolved were encapsulated with the thiolate shells, and exhibited striking propensities of forming long-range ordered arrays. The morphological and structural evolutions were characterized using transmission electron microscopy, X-ray diffraction, UV−vis and infrared spectroscopies. Although temperature-driven crystal growth is known for nonencapsulated particles, the evolution of the thiolate-encapsulated nanoparticles in solutions into well-defined morphologies represents an intriguing example of temperature manipulations in size monodispersity and shape control.
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Metadata
- Authors
- Maye, M. M., Zheng, W., Leibowitz, F. L., Ly, N. K., & Zhong, C.-J.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-11-04
- Volume
- 16
- Issue
- 2
- Pages
- 490-497
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W1971078151
- Cited by
- 321
- References
- 27
- FWCI
- 11.27
- Type
- journal article
- Language
- en
- Open access
- closed
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