The DOI matches its Crossref record.
Atom Transfer Radical Copolymerization of Methyl Methacrylate and n-Butyl Acrylate
Abstract
Copolymers of methyl methacrylate and n -butyl acrylate were prepared using atom transfer radical polymerization catalyzed by CuBr/4,4‘-di(5-nonyl)-2,2‘-bipyridine (dNbpy), CuBr/ N,N, N ‘, N ‘ ‘, N ‘ ‘-pentamethyldiethylenetriamine (PMDETA), and CuBr/tris[2-(dimethylamino)ethyl]amine (Me 6 TREN). Point estimates and 95% joint confidence intervals of the reactivity ratios were calculated for the copolymerizations catalyzed by CuBr/dNbpy ( r MMA = 2.52, r BA = 0.265) and those catalyzed by CuBr/PMDETA ( r MMA = 3.15, r BA = 0.37) using previously described least-squares calculations. Semilogarithimic plots of monomer conversion vs time were nearly linear. Plots of M n vs monomer conversion were linear, and polydispersity decreased with increasing monomer conversion. Copolymerizations were simulated using Predici 5.3.2 in order to better understand the experimentally observed results.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Self-citationNitroxide-mediated polymerization
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., & Charleux, B. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.002 · Cited by 1,380
Marrying click chemistry with polymerization: expanding the scope of polymeric materials
Golas, P. L., & Matyjaszewski, K. (2010) · Chem. Soc. Rev. · doi:10.1039/b901978m · Cited by 863
Self-citationSARA ATRP or SET-LRP. End of controversy?
Konkolewicz, D., Wang, Y., Krys, P., Zhong, M., Isse, A. A., Gennaro, A., & Matyjaszewski, K. (2014) · Polymer Chemistry · doi:10.1039/c4py00149d · Cited by 314
Self-citationModeling and theoretical development in controlled radical polymerization
Mastan, E., Li, X., & Zhu, S. (2015) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2014.12.003 · Cited by 131
Metadata
- Authors
- Ziegler, M. J., & Matyjaszewski, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-01-01
- Volume
- 34
- Issue
- 3
- Pages
- 415-424
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2038336213
- Cited by
- 162
- References
- 0
- FWCI
- 6.69
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Atom Transfer Radical Copolymerization of Methyl Methacrylate and n-Butyl Acrylate. https://app.cochat.ai/papers/10.1021/ma001182k
- The paper
- Ziegler, M. J., & Matyjaszewski, K. (2001). Atom Transfer Radical Copolymerization of Methyl Methacrylate and n-Butyl Acrylate. Macromolecules. https://doi.org/10.1021/ma001182k
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
