The DOI matches its Crossref record; 16 of the 16 references it cites were found in a registry or an index.
Evidence of Elongated Polymeric Aggregates in Nafion
Abstract
Small-angle X-ray and neutron-scattering techniques have been used to probe the structure of swollen Nafion membranes in the range 10−10000 Å. From analyzing the scattering data as a function of the polymer volume fraction and using a contrast variation method for the neutron experiments, we suggest a new structural model of Nafion in the hydrated state. It is based on the aggregation of the ionomer chains into elongated polymeric bundles with a diameter on the order of 40 Å and a length larger than 1000 Å, surrounded by the electrolyte solution.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells
Kreuer, K. D. (2001) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)00632-3 · Cited by 2,969
(2013) · Mean Field Simulation for Monte Carlo Integration · doi:10.1201/b14924-7 · Cited by 1,554
Scattering by an Inhomogeneous Solid. II. The Correlation Function and Its Application
Debye, P., Anderson, H. R., & Brumberger, H. (1957) · Journal of Applied Physics · doi:10.1063/1.1722830 · Cited by 1,451
Gierke, T. D., Munn, G. E., & Wilson, F. C. (1981) · Journal of Polymer Science: Polymer Physics Edition · doi:10.1002/pol.1981.180191103 · Cited by 1,434
Structural evolution of water swollen perfluorosulfonated ionomers from dry membrane to solution
Gebel, G. (2000) · Polymer · doi:10.1016/s0032-3861(99)00770-3 · Cited by 878
Self-citationClustering of Ions in Organic Polymers. A Theoretical Approach
Eisenberg, A. (1970) · Macromolecules · doi:10.1021/ma60014a006 · Cited by 654
Perfluorinated Ionomer Membranes
(1982) · ACS Symposium Series · doi:10.1021/bk-1982-0180 · Cited by 593
Fujimura, M., Hashimoto, T., & Kawai, H. (1981) · Macromolecules · doi:10.1021/ma50006a032 · Cited by 399
Small-Angle Scattering Study of Water-Swollen Perfluorinated Ionomer Membranes
Gebel, G., & Lambard, J. (1997) · Macromolecules · doi:10.1021/ma970801v · Cited by 305
Self-citationSAXS and USAXS on the high brilliance beamline at the ESRF
Narayanan, T., Diat, O., & Bösecke, P. (2001) · Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment · doi:10.1016/s0168-9002(01)00553-8 · Cited by 267
Self-citationSmall-Angle Scattering Study of Perfluorosulfonated Ionomer Solutions
Loppinet, B., Gebel, G., & Williams, C. E. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp9623047 · Cited by 199
Self-citationStructure and Properties of Ionomers
Pinéri, M., & Eisenberg, A. (1987) · Springer eBooks · doi:10.1007/978-94-009-3829-8 · Cited by 182
Elliott, J. A., Hanna, S., Elliott, A. M. S., & Cooley, G. E. (2000) · Macromolecules · doi:10.1021/ma991113+ · Cited by 164
Equilibrium Aggregation in Perfluorinated Ionomer Solutions
Cirkel, P. A., Okada, T., & Kinugasa, S. (1998) · Macromolecules · doi:10.1021/ma981421s · Cited by 60
Percolation conductivity in Nafion membranes
Wódzki, R., Narȩbska, A., & Nioch, W. K. (1985) · Journal of Applied Polymer Science · doi:10.1002/app.1985.070300225 · Cited by 56
A Comparison of Mechanical and Electrical Percolation during the Gelling of Nafion Solutions
Cirkel, P. A., & Okada, T. (2000) · Macromolecules · doi:10.1021/ma992031o · Cited by 29
Cited by
State of Understanding of Nafion
Mauritz, K. A., & Moore, R. B. (2004) · Chemical Reviews · doi:10.1021/cr0207123 · Cited by 4,791
New Insights into Perfluorinated Sulfonic-Acid Ionomers
Kusoglu, A., & Weber, A. Z. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00159 · Cited by 2,432
Parallel cylindrical water nanochannels in Nafion fuel-cell membranes
Schmidt-Rohr, K., & Chen, Q. (2008) · Nature Materials · doi:10.1038/nmat2074 · Cited by 1,371
Structure‐Morphology‐Property Relationships of Non‐Perfluorinated Proton‐Conducting Membranes
Peckham, T. J., & Holdcroft, S. (2010) · Advanced Materials · doi:10.1002/adma.201001164 · Cited by 622
Design and properties of functional hybrid organic–inorganic membranes for fuel cells
Laberty-Robert, C., Vallé, K., Pereira, F., & Sanchez, C. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00144a · Cited by 527
Metadata
- Authors
- Rubatat, L., Rollet, A. L., Gebel, G., & Diat, O.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-04-09
- Volume
- 35
- Issue
- 10
- Pages
- 4050-4055
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2063239405
- Cited by
- 503
- References
- 16
- FWCI
- 10.52
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
