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Photopolymerizations of Thiol−Ene Polymers without Photoinitiators
Abstract
A thiol monomer is shown to copolymerize with vinyl ether, allyl, acrylate, methacrylate, and vinylbenzene monomers. These thiol−ene polymerizations are photoinitiated without the use of photoinitiator molecules. It is seen that the polymerization proceeds more readily when initiatorless samples are irradiated with light centered around 254 nm as compared to 365 nm light. To demonstrate resistance to oxygen inhibition, thin polymer films of 3−15 μm are polymerized while exposed to ambient air. Without photoinitiator molecules present, light is attenuated only by the monomer and polymer. This feature leads to greater penetration of ultraviolet light and allows for the polymerization of extremely thick polymers. Thick cures of up to 25 in. are obtained using a thiol−vinyl ether system.
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Citations
Cited by
Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis
Hoyle, C. E., Lowe, A. B., & Bowman, C. N. (2010) · Chemical Society Reviews · doi:10.1039/b901979k · Cited by 1,639
Self-citationThiol–enes: Chemistry of the past with promise for the future
Hoyle, C. E., Lee, T. Y., & Roper, T. (2004) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.20366 · Cited by 1,457
Strategies to Reduce Oxygen Inhibition in Photoinduced Polymerization
Ligon, S. C., Husár, B., Wutzel, H., Holman, R., & Liska, R. (2014) · Chemical Reviews · doi:10.1021/cr3005197 · Cited by 721
Click chemistry strategies for the accelerated synthesis of functional macromolecules
Geng, Z., Shin, J. J., Xi, Y., & Hawker, C. J. (2021) · Journal of Polymer Science · doi:10.1002/pol.20210126 · Cited by 269
Thiol-ene-methacrylate composites as dental restorative materials
Boulden, J. E., Cramer, N. B., Schreck, K. M., Couch, C. L., Bracho-Troconis, C., Stansbury, J. W., & Bowman, C. N. (2011) · Dental Materials · doi:10.1016/j.dental.2010.11.001 · Cited by 93
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Metadata
- Authors
- Cramer, N. B., Scott, J. P., & Bowman, C. N.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-05-31
- Volume
- 35
- Issue
- 14
- Pages
- 5361-5365
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2004988762
- Cited by
- 353
- References
- 0
- FWCI
- 6.84
- Type
- journal article
- Language
- en
- Open access
- closed
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