The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Structural Characterization of Nitroxide-Terminated Poly(n-butyl acrylate) Prepared in Bulk and Miniemulsion Polymerizations
Abstract
The structure of “living” poly( n -butyl acrylate) homopolymers prepared via nitroxide-mediated controlled radical polymerization in bulk and in miniemulsion at 112 °C was examined by SEC, NMR, and MALDI−TOF mass spectrometry in order to study the influence of chain transfer to polymer. The absence of detectable terminal unsaturation was confirmed by proton NMR. The branched structure was observed by 13 C NMR. MALDI−TOF MS demonstrated that the majority of chains, even at high conversion, had the ideal structure with one initiator fragment and one nitroxide end group. From these results, we concluded that intramolecular chain transfer occurred (presumably by backbiting) and was the predominant mechanism throughout the polymerization at 112 °C.
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Cites
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Kato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Controlled/living radical polymerization in aqueous media: homogeneous and heterogeneous systems
Qiu, J., Charleux, B., & Matyjaszewski, K. (2001) · Progress in Polymer Science · doi:10.1016/s0079-6700(01)00033-8 · Cited by 595
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Controlled/Living Radical Polymerization in Dispersed Systems
Zetterlund, P. B., Kagawa, Y., & Okubo, M. (2008) · Chemical Reviews · doi:10.1021/cr800242x · Cited by 677
Well-Defined Protein−Polymer Conjugates via in Situ RAFT Polymerization
Boyer, C., Bulmus, V., Liu, J., Davis, T. P., Stenzel, M. H., & Barner-Kowollik, C. (2007) · Journal of the American Chemical Society · doi:10.1021/ja070956a · Cited by 411
Metadata
- Authors
- Farcet, C., Belleney, J., Charleux, B., & Pirri, R.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-05-24
- Volume
- 35
- Issue
- 13
- Pages
- 4912-4918
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2071313931
- Cited by
- 163
- References
- 3
- FWCI
- 8.56
- Type
- journal article
- Language
- en
- Open access
- closed
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