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Cited by 210

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Thermoresponsive Micellization of Poly(ethylene glycol)-b-poly(N-isopropylacrylamide) in Water

Zhang, Wangqing, Shi, Linqi, Wu, Kai, An, Yingli·2005·Macromolecules

Abstract

Thermoresponsive micellization of poly(ethylene glycol)- b -poly( N -isopropylacrylamide) (PEG 110 - b -PNIPAM 44 ) in water is studied by static light scattering and dynamic light scattering. The critical aggregation temperature of PEG 110 - b -PNIPAM 44 is a little higher than homopolymer PNIPAM, and it depends on the block copolymer concentration, which increases from 33.7 to 38.4°C when the copolymer concentration decreases from 2.0 to 0.20 mg/mL. Above the critical aggregation temperature, thermoresponsive micellization occurs, and the resultant spherical micelles consist of a PNIPAM core and a PEG shell. The block copolymer concentration exerts a strong influence on the size and structure of the resultant micelles. Micellization of PEG 110 - b -PNIPAM 44 at higher copolymer concentration favors formation of narrowly distributed, small, and dense micelles, while large, loose micelles or micellar clusters form at lower block copolymer concentration.

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Metadata

Authors
Zhang, W., Shi, L., Wu, K., & An, Y.
Venue
Macromolecules
Published
2005-06-01
Volume
38
Issue
13
Pages
5743-5747
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
OpenAlex
W1988450210
Cited by
210
References
1
FWCI
8.14
Type
journal article
Language
en
Open access
closed

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