The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
One-Pot Synthesis of ABC Type Triblock Copolymers via in situ Click [3 + 2] and Diels−Alder [4 + 2] Reactions
Abstract
We report a one-pot synthesis of ABC triblock copolymers of poly(ethylene glycol)− (PEG−) polystyrene− (PS−) poly(methyl methacrylate) (PMMA), and poly(ε-caprolactone)− (PCL−) PS−PMMA by combining in situ click [3 + 2] and Diels−Alder [4 + 2] reactions. For this purpose, furan-protected maleimide end-functionalized PMMA, PS with α-anthracene and ω-azide end-functionality, and PEG or PCL with an alkyne end-functional group were reacted in N, N -dimehtylformamide (DMF) for 36 h at 120 °C in order to give the corresponding triblock copolymers. All polymeric precursors with narrow molecular weight distribution and well-defined chain-end functionalities were achieved from living polymerization methods, except PEG. The obtained polymers were characterized by 1 H NMR (250 MHz), gel permeation chromatography (GPC), and differential scanning calorimetry (DSC) measurements.
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Citations
Cites
PEG- and Peptide-Grafted Aliphatic Polyesters by Click Chemistry
Parrish, B., Breitenkamp, R. B., & Emrick, T. (2005) · Journal of the American Chemical Society · doi:10.1021/ja050310n · Cited by 579
Cited by
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Marrying click chemistry with polymerization: expanding the scope of polymeric materials
Golas, P. L., & Matyjaszewski, K. (2010) · Chem. Soc. Rev. · doi:10.1039/b901978m · Cited by 863
“Click”‐Chemistry in Polymer and Material Science: the Update
Binder, W. H. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800332 · Cited by 567
Johnson, J. A., Finn, M. G., Koberstein, J. T., & Turro, N. J. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800208 · Cited by 320
Kerkel, F., Markiewicz, M., Stolte, S., Müller, E., & Kunz, W. (2021) · Green Chemistry · doi:10.1039/d0gc04353b · Cited by 221
Metadata
- Authors
- Durmaz, H., Dag, A., Altintas, O., Erdogan, T., Hizal, G., & Tunca, U.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-12-21
- Volume
- 40
- Issue
- 2
- Pages
- 191-198
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2092722830
- Cited by
- 238
- References
- 1
- FWCI
- 12.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- Durmaz, H., Dag, A., Altintas, O., Erdogan, T., Hizal, G., & Tunca, U. (2007). One-Pot Synthesis of ABC Type Triblock Copolymers via in situ Click [3 + 2] and Diels−Alder [4 + 2] Reactions. Macromolecules. https://doi.org/10.1021/ma061819l
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
