The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Synthesis of Photocleavable Linear Macromonomers by ATRP and Star Macromonomers by a Tandem ATRP−Click Reaction: Precursors to Photodegradable Model Networks
Abstract
Atom transfer radical polymerization (ATRP) and the copper-catalyzed azide−alkyne cycloaddition (CuAAC) were utilized for the synthesis of photodegradable polymeric materials by two complementary schemes. Linear azido-telechelic macromonomers possessing a photocleavable functionality at the center were synthesized by ATRP and subsequent end-group modification. These macromonomers were cross-linked with a tetrafunctional alkyne by CuAAC to form insoluble materials which degraded upon exposure to UV light of 350 nm to yield soluble star polymer products of defined molecular weight. Complementary to this approach, four-armed star polymers possessing photocleavable arms and terminal azides were prepared by a novel one-pot CuAAC/ATRP reaction followed by end-group modification. These star polymers were cross-linked with a linear, bifunctional alkyne to yield insoluble materials which, upon exposure to UV light, degraded to yield linear polymers of defined molecular weight.
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Cites
Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696
Poirier, Y., Nawrath, C., & Somerville, C. (1995) · Nature Biotechnology · doi:10.1038/nbt0295-142 · Cited by 480
Johnson, R. M., & Fraser, C. L. (2004) · Biomacromolecules · doi:10.1021/bm034421v · Cited by 46
Cited by
Zhang, Z. P., Rong, M. Z., & Zhang, M. Q. (2018) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.03.002 · Cited by 586
“Click”‐Chemistry in Polymer and Material Science: the Update
Binder, W. H. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800332 · Cited by 567
Tardy, A., Nicolas, J., Gigmes, D., Lefay, C., & Guillaneuf, Y. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00319 · Cited by 469
Advances in Bioactive Hydrogels to Probe and Direct Cell Fate
DeForest, C. A., & Anseth, K. S. (2012) · Annual Review of Chemical and Biomolecular Engineering · doi:10.1146/annurev-chembioeng-062011-080945 · Cited by 323
Johnson, J. A., Finn, M. G., Koberstein, J. T., & Turro, N. J. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800208 · Cited by 320
Self-citationvan Dijk, M., Rijkers, D. T. S., Liskamp, R. M. J., van Nostrum, C. F., & Hennink, W. E. (2009) · Bioconjugate Chemistry · doi:10.1021/bc900087a · Cited by 300
Development of materials and technologies for control of polymer recycling
Nishida, H. (2011) · Polymer Journal · doi:10.1038/pj.2011.16 · Cited by 94
Metadata
- Authors
- Johnson, J. A., Finn, M. G., Koberstein, J. T., & Turro, N. J.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-03-31
- Volume
- 40
- Issue
- 10
- Pages
- 3589-3598
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2172129325
- Cited by
- 162
- References
- 3
- FWCI
- 7.87
- Type
- journal article
- Language
- en
- Open access
- closed
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