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Cited by 292

The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.

Graft Copolymers by a Combination of ATRP and Two Different Consecutive Click Reactions

Tsarevsky, Nicolay V., Bencherif, Sidi A., Matyjaszewski, Krzysztof·2007·Macromolecules

Abstract

The epoxide ring in glycidyl butyrate (model compound) and in well-defined copolymers of glycidyl methacrylate (<40 mol %) and methyl methacrylate prepared by ATRP was efficiently opened with sodium azide in the presence of ammonium chloride in DMF at 50 °C. This click-type reaction led to the formation of the corresponding 1-hydroxy-2-azido compounds in high yields. The prepared azide-containing copolymers were functionalized in a second click reaction, the room temperature CuBr/ N,N, N ‘, N ‘ ‘, N ‘ ‘-pentamethyldiethylenetriamine-catalyzed 1,3-dipolar cycloaddition, of poly(ethylene oxide) methyl ether pentynoate to yield loosely grafted polymeric brushes with hydrophilic PEO side chains.

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Crossref · 10.1021/ma070705m

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Metadata

Authors
Tsarevsky, N. V., Bencherif, S. A., & Matyjaszewski, K.
Venue
Macromolecules
Published
2007-05-27
Volume
40
Issue
13
Pages
4439-4445
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
OpenAlex
W2057581784
Cited by
292
References
5
FWCI
14.48
Type
journal article
Language
en
Open access
closed

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