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Verification of Controlled Grafting of Styrene from Cellulose via Radiation-Induced RAFT Polymerization
Abstract
Reversible addition−fragmentation chain transfer (RAFT) polymerization was applied to radiation-induced graft polymerization of styrene from cellulose. The grafting of styrene from cellulose substrates using the chain transfer agent cumyl phenyldithioacetate was confirmed by Raman and X-ray photoelectron spectroscopy, differential scanning calorimetery, thermogravimetric analysis, scanning electron microscopy, and contact angle analysis. Grafted polystyrene chains were cleaved from the cellulose surface by acidic hydrolysis of the cellulose. The number-average molecular weight and polydispersity index of the grafted and the free (nongrafted) polystyrenes obtained under identical conditions were determined by size exclusion chromatography. Grafted and nongrafted polystyrenes have almost the same (near theoretical) molecular weight and narrow polydispersity, thus proving for the first time the control of the grafting process mediated via RAFT without any prior functionalization of the surface.
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Cited by
Barbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Zoppe, J. O., Ataman, N. C., Mocny, P., Wang, J., Moraes, J., & Klok, H.-A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00314 · Cited by 1,046
Bioapplications of RAFT Polymerization
Boyer, C., Bulmus, V., Davis, T. P., Ladmiral, V., Liu, J., & Perrier, S. (2009) · Chemical Reviews · doi:10.1021/cr9001403 · Cited by 1,015
Self-citation'Green' reversible addition-fragmentation chain-transfer (RAFT) polymerization
Semsarilar, M., & Perrier, S. (2010) · Nature Chemistry · doi:10.1038/nchem.853 · Cited by 314
Surface functionalization of biomaterials by radical polymerization
Zhou, T., Zhu, Y., Li, X., Liu, X., Yeung, K. W. K., Wu, S., Wang, X., Cui, Z., Yang, X., & Chu, P. K. (2016) · Progress in Materials Science · doi:10.1016/j.pmatsci.2016.04.005 · Cited by 145
Metadata
- Authors
- Barsbay, M., Güven, O., Stenzel, M. H., Davis, T. P., Barner-Kowollik, C., & Barner, L.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-08
- Volume
- 40
- Issue
- 20
- Pages
- 7140-7147
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2026310802
- Cited by
- 189
- References
- 0
- FWCI
- 5.90
- Type
- journal article
- Language
- en
- Open access
- closed
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- Barsbay, M., Güven, O., Stenzel, M. H., Davis, T. P., Barner-Kowollik, C., & Barner, L. (2007). Verification of Controlled Grafting of Styrene from Cellulose via Radiation-Induced RAFT Polymerization. Macromolecules. https://doi.org/10.1021/ma070825u
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