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A Soluble and Conductive Polyfluorene Ionomer with Pendant Imidazolium Groups for Alkaline Fuel Cell Applications
Abstract
Solvent processable polyfluorene ionomers with pendant imidazolium groups were synthesized and characterized. The synthesized polymeric membranes are transparent, flexible, and mechanically strong and exhibit hydroxide ion conductivity above 10 –2 S/cm at room temperature. The membranes are soluble in polar aprotic solvents such as DMSO and DMF, while insoluble in water and aqueous methanol. The solubility properties of polyfluorene ionomers enable the use for not only alkaline anion-exchange membrane but also ionomer electrode material. 1 H NMR and hydroxide ion conductivity measurements demonstrated an excellent chemical stability of the synthesized polyfluorene ionomers in high-pH solution at elevated temperatures. The results of the study suggest a feasible approach for the synthesis and practical applications of alkaline anion-exchange membranes (AEMs).
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Cites
Cleaning the air and improving health with hydrogen fuel-cell vehicles
Jacobson, M. Z., Colella, W. G., & Golden, D. M. (2005) · Science · doi:10.1126/science.1109157 · Cited by 1,023
Imidazolium functionalized polysulfone anion exchange membrane for fuel cell application
Zhang, F., Zhang, H., & Qu, C. (2011) · Journal of Materials Chemistry · doi:10.1039/c1jm10656b · Cited by 302
Cited by
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Anion exchange membrane fuel cells: Current status and remaining challenges
Gottesfeld, S., Dekel, D. R., Page, M., Bae, C., Yan, Y., Zelenay, P., & Kim, Y. S. (2018) · Journal of Power Sources · doi:10.1016/j.jpowsour.2017.08.010 · Cited by 895
Arges, C. G., & Ramani, V. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1217215110 · Cited by 494
Hugar, K. M., Kostalik, H. A., & Coates, G. W. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02879 · Cited by 465
Alkaline stability of poly(phenylene)‐based anion exchange membranes with various cations
Hibbs, M. R. (2013) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.23149 · Cited by 282
Metadata
- Authors
- Lin, B., Qiu, L., Qiu, B., Peng, Y., & Yan, F.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-11-30
- Volume
- 44
- Issue
- 24
- Pages
- 9642-9649
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2329528504
- Cited by
- 262
- References
- 2
- FWCI
- 16.93
- Type
- journal article
- Language
- en
- Open access
- closed
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