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The Glass Temperature of Linear Polyethylene
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTThe Glass Temperature of Linear PolyethyleneFerdinand C. Stehling and Leo MandelkernCite this: Macromolecules 1970, 3, 2, 242–252Publication Date (Print):March 1, 1970Publication History Published online1 May 2002Published inissue 1 March 1970https://pubs.acs.org/doi/10.1021/ma60014a023https://doi.org/10.1021/ma60014a023research-articleACS PublicationsRequest reuse permissionsArticle Views1263Altmetric-Citations258LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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“The glass transition temperatures of linear polyethylenes are generally agreed to occur between approximately -120 °C and -50 °C ( 50, 51 ).”
From Chemically recyclable polyolefin-like multiblock polymers (2023) · cites this paper as [51]
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“The one detected at the lowest temperature at around -125 °C is usually assigned to the movement of methylene units [59-62], the transition appearing around -20 °C belongs to the movement of branches [60-64], while the highest to the transition of segments attached to crystals [59,65] or in our cases also to ionic clu…”
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“The β-relaxation is believed to be caused by the motion of branches in the amorphous matrix [32, 36].”
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“Although there is no concrete data sheet information on the glass transition temperature Tg of the HDPE type investigated, for linear polyethylene the γ - transition at −130 °C can be stated as the primary glass transition (Stehling and Mandelkern 1970).”
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Metadata
- Authors
- Stehling, F. C., & Mandelkern, L.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1970-03
- Volume
- 3
- Issue
- 2
- Pages
- 242-252
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2082318623
- Cited by
- 278
- References
- 0
- Citations by year
- 2026: 3 · 2025: 1 · 2024: 4 · 2023: 4 · 2022: 4 · 2021: 6 · 2020: 5 · 2019: 5 · 2018: 4 · 2017: 7 · 2016: 6 · 2015: 4 · 2014: 3 · 2013: 5 · 2012: 8
- FWCI
- 14.94
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Material Dynamics and Properties
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Rheology and Fluid Dynamics Studies
- Keywords
- glass transition temperature, linear polyethylene, polyethylene, chain conformation
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