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An Imidazole-Functionalized Polyfluorene Derivative as Sensitive Fluorescent Probe for Metal Ions and Cyanide

Li, Zhong’an, Lou, Xiaoding, Yu, Haibo, Li, Zhen, Qin, Jingui·2008·Macromolecules

Abstract

To develop sensitive and selective CN − chemosensors, a new imidazole-functionalized polyfluorene ( P1 ) was designed and obtained conveniently, the fluorescence of which could be completely quenched by Cu 2+ ions at the concentration as low as 0.20 ppm in diluted solutions. By utilizing the much higher stability constant of the complex of CN − and Cu 2+, the quenched fluorescence of the solution of P1 by Cu 2+ ions could recover upon the addition of trace CN − anions, with the detection limit down to 0.31 ppm, making P1 a novel, sensitive and selective cyanide probe.

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Metadata

Authors
Li, Z., Lou, X., Yu, H., Li, Z., & Qin, J.
Venue
Macromolecules
Published
2008-10-04
Volume
41
Issue
20
Pages
7433-7439
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
OpenAlex
W1980010612
Cited by
193
References
0
FWCI
7.20
Type
journal article
Language
en
Open access
closed

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Li, Z., Lou, X., Yu, H., Li, Z., & Qin, J. (2008). An Imidazole-Functionalized Polyfluorene Derivative as Sensitive Fluorescent Probe for Metal Ions and Cyanide. Macromolecules. https://doi.org/10.1021/ma8013096

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