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Star Polymers and Nanospheres from Cross-Linkable Diblock Copolymers
Abstract
Polystyrene- block -poly(2-cinnamoylethyl methacrylate) (PS- b -PCEMA) formed micelles in THF/cyclohexane or chloroform/cyclohexane mixtures with the PCEMA block as the core. Depending on the relative length of the PS and PCEMA block, star and crewcut micelles were prepared. Upon UV irradiation, the PCEMA block selectively cross-linked to form star polymers and nanospheres from the corresponding star and crewcut micelles. The cross-linked micelles were characterized by solution and solid-state NMR, FTIR, GPC, TEM, and dynamic and static light scattering.
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Citations
Cited by
Block copolymer micelles for drug delivery: design, characterization and biological significance
Kataoka, K., Harada, A., & Nagasaki, Y. (2001) · Advanced Drug Delivery Reviews · doi:10.1016/s0169-409x(00)00124-1 · Cited by 3,506
Cross-linked block copolymer micelles: functional nanostructures of great potential and versatility
O'Reilly, R. K., Hawker, C. J., & Wooley, K. L. (2006) · Chemical Society Reviews · doi:10.1039/b514858h · Cited by 939
Recent advances in shell cross-linked micelles
Read, E. S., & Armes, S. P. (2007) · Chemical Communications · doi:10.1039/b701217a · Cited by 401
Design of reversibly core cross-linked micelles sensitive to reductive environment
Cajot, S., Lautram, N., Passirani, C., & Jérôme, C. (2011) · Journal of Controlled Release · doi:10.1016/j.jconrel.2011.03.026 · Cited by 76
Metadata
- Authors
- Guo, A., Liu, G., & Tao, J.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 29
- Issue
- 7
- Pages
- 2487-2493
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2094536476
- Cited by
- 346
- References
- 0
- FWCI
- 12.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Guo, A., Liu, G., & Tao, J. (1996). Star Polymers and Nanospheres from Cross-Linkable Diblock Copolymers. Macromolecules. https://doi.org/10.1021/ma951354r
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
