The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Initiating Systems for Nitroxide-Mediated “Living” Free Radical Polymerizations: Synthesis and Evaluation
Abstract
A variety of initiating systems for the preparation of macromolecules by nitroxide-mediated “living” free radical procedures have been prepared and evaluated. The systems can be divided into two classes, unimolecular initiators in which alkylated TEMPO (2,2,6,6-tetramethylpiperidinyloxy) derivatives dissociate to provide both the initiating radical and the stable radical, and bimolecular systems in which a traditional free radical initiator, such as BPO or AIBN, is used in conjunction with TEMPO. For the unimolecular initiators it was found that an α-methyl group is essential for “living” character, while a variety of substituents could be placed on the phenyl ring or the β-carbon atom without affecting the efficiency of the unimolecular initiator. It was also found that the rate of polymerization is approximately the same for both the unimolecular and corresponding bimolecular systems; however, the unimolecular initiators afforded better control over molecular weight and polydispersity.
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Cites
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Barbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Nitroxide-mediated polymerization
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., & Charleux, B. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.002 · Cited by 1,380
Metal-catalyzed immortal ring-opening polymerization of lactones, lactides and cyclic carbonates
Ajellal, N., Carpentier, J.-F., Guillaume, C., Guillaume, S. M., Helou, M., Poirier, V., Sarazin, Y., & Trifonov, A. (2010) · Dalton Transactions · doi:10.1039/c001226b · Cited by 494
Benoit, D., Harth, E., Fox, P., Waymouth, R. M., & Hawker, C. J. (2000) · Macromolecules · doi:10.1021/ma991187l · Cited by 216
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Metadata
- Authors
- Hawker, C. J., Barclay, G. G., Orellana, A., Dao, J., & Devonport, W.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 29
- Issue
- 16
- Pages
- 5245-5254
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1967299069
- Cited by
- 355
- References
- 1
- FWCI
- 16.15
- Type
- journal article
- Language
- en
- Open access
- closed
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