The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Living Radical Polymerization of Alkyl Methacrylates with Ruthenium Complex and Synthesis of Their Block Copolymers
Abstract
Living radical polymerizations of ethyl and n -butyl methacrylates (EMA and BMA, respectively) have been achieved with ternary initiating systems that consist of carbon tetrachloride, tris(triphenylphosphine)ruthenium dichloride [RuCl 2 (PPh 3 ) 3 ], and aluminum compounds such as MeAl(ODBP) 2 (ODBP, 2,6-di- tert -butylphenoxy) and Al(O i Pr) 3 in toluene at 60−80 °C. The produced polymers had narrow molecular weight distributions (MWDs) ( M̄ w / M̄ n = 1.2−1.5) and controlled molecular weights that are nearly proportional to monomer conversion. Sequential living polymerizations of these methacrylates from methyl methacrylate (MMA) afforded AB-type block copolymers with narrow MWDs ( M̄ w / M̄ n ∼ 1.2). Further addition of MMA into the living AB block copolymers gave ABA-type triblock copolymers poly(MMA- b -BMA- b -MMA).
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Citations
Cites
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Kato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Self-citationWang, J.-S., & Matyjaszewski, K. (1995) · Macromolecules · doi:10.1021/ma00126a041 · Cited by 486
Cited by
Metal-Catalyzed Living Radical Polymerization
Kamigaito, M., Ando, T., & Sawamoto, M. (2001) · Chemical Reviews · doi:10.1021/cr9901182 · Cited by 3,275
Self-citationOuchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Self-citationSynthesis of Acrylate and Methacrylate Block Copolymers Using Atom Transfer Radical Polymerization
Shipp, D. A., Wang, J.-L., & Matyjaszewski, K. (1998) · Macromolecules · doi:10.1021/ma981033q · Cited by 351
Martín‐Gomis, L., Fernández‐García, M., de la Fuente, J. L., Madruga, E. L., & Cerrada, M. L. (2003) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200300001 · Cited by 12
Metadata
- Authors
- Kotani, Y., Kato, M., Kamigaito, M., & Sawamoto, M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1996-01-01
- Volume
- 29
- Issue
- 22
- Pages
- 6979-6982
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1991110829
- Cited by
- 161
- References
- 3
- FWCI
- 7.78
- Type
- journal article
- Language
- en
- Open access
- closed
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