The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Kinetic Study of the Homogeneous Atom Transfer Radical Polymerization of Methyl Methacrylate
Abstract
The homogeneous controlled/“living” radical polymerization of methyl methacrylate (MMA) using the atom transfer radical polymerization (ATRP) with CuCl/4,4‘-di(5-nonyl)-2,2‘-bipyridine catalytic system and diphenyl ether as the solvent generated well-defined polymers with polydispersities M w / M n ≤ 1.2. The evolution of the molecular weights of the polymers follows the ratio of the mass of the consumed monomer to the initial initiator concentration. The rate of polymerization follows first-order kinetics with respect to the decrease of monomer concentration. The polymerization rate reaches a maximum when the ratio of ligand-to-Cu I Cl is one-to-one. ATRP of MMA shows first-order kinetics with respect to both Cu I Cl and the initiator, alkyl or sulfonyl chloride. The rate of polymerization did not obey simple negative first-order kinetics with respect to the concentration of Cu II Cl, partially due to a persistent radical effect, which resulted in the increase of [Cu II Cl] in the initial stage of polymerization. Thermodynamic data and activation parameters for the solution ATRP of MMA are reported.
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Cites
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Self-citationKato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Cited by
Kinetics of living radical polymerization
Goto, A., & Fukuda, T. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.01.002 · Cited by 914
Synthesis of Acrylate and Methacrylate Block Copolymers Using Atom Transfer Radical Polymerization
Shipp, D. A., Wang, J.-L., & Matyjaszewski, K. (1998) · Macromolecules · doi:10.1021/ma981033q · Cited by 351
Self-citationAtom Transfer Radical Polymerization of 2-Hydroxyethyl Methacrylate
Beers, K. L., Boo, S., Gaynor, S. G., & Matyjaszewski, K. (1999) · Macromolecules · doi:10.1021/ma990176p · Cited by 288
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Metadata
- Authors
- Wang, J.-L., Grimaud, T., & Matyjaszewski, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-10-01
- Volume
- 30
- Issue
- 21
- Pages
- 6507-6512
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2056201335
- Cited by
- 192
- References
- 2
- FWCI
- 10.51
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, J.-L., Grimaud, T., & Matyjaszewski, K. (1997). Kinetic Study of the Homogeneous Atom Transfer Radical Polymerization of Methyl Methacrylate. Macromolecules. https://doi.org/10.1021/ma970636j
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