The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
Controlled/“Living” Radical Polymerization. Atom Transfer Radical Polymerization Using Multidentate Amine Ligands
Abstract
Three multidentate amines, tetramethylethylenediamine (TMEDA), N,N,N ‘,N ‘,N ‘‘-pentamethyldiethylenetriamine (PMDETA) and 1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) have been successfully used as new ligands in the copper mediated atom transfer radical polymerization (ATRP) of styrene, methyl acrylate and methyl methacrylate. All the polymerizations were well controlled with a linear increase of molecular weights ( M n ) with conversion and relatively low polydispersities throughout the reactions. Compared to the 2,2‘-bipyridine (bipy) based ligands, most multidentate amines are less expensive and the polymerization mixtures are less colored. In particular, the use of the tridentate PMDETA and the tetradentate HMTETA as the ligands resulted in faster polymerization rates for styrene and methyl acrylate than those using bipy as the ligand. This may be in part attributed to the fact that the coordination complexes between copper and the simple amines have lower redox potentials than the copper−bipy complex, resulting in higher rates of activation of the dormant halides. Additional rate effects may originate from the solubilities of the copper(I) and copper(II) complexes. The new ligands are very attractive alternatives to bipy and its derivatives as ligands.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Self-citationKato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Wang, J.-S., & Matyjaszewski, K. (1995) · Macromolecules · doi:10.1021/ma00127a042 · Cited by 1,701
Self-citationMatyjaszewski, K., Patten, T. E., & Xia, J. (1997) · Journal of the American Chemical Society · doi:10.1021/ja963361g · Cited by 891
Self-citationPolymers with Very Low Polydispersities from Atom Transfer Radical Polymerization
Patten, T. E., Xia, J., Abernathy, T., & Matyjaszewski, K. (1996) · Science · doi:10.1126/science.272.5263.866 · Cited by 866
Self-citation"Living" Radical Polymerization of Styrene Initiated by Arenesulfonyl Chlorides and CuI(bpy)nCl
Percec, V., & Barboiu, B. (1995) · Macromolecules · doi:10.1021/ma00127a057 · Cited by 832
Molecular Weight Control by a "Living" Free-Radical Polymerization Process
Hawker, C. J. (1994) · Journal of the American Chemical Society · doi:10.1021/ja00103a055 · Cited by 588
Granel, C., Dubois, P., Jérôme, R., & Teyssié, P. (1996) · Macromolecules · doi:10.1021/ma9608380 · Cited by 554
Keller, R. N., Wrcoff, H. D., & Marchi, L. E. (1946) · Inorganic Syntheses · doi:10.1002/9780470132333.ch1 · Cited by 487
Haddleton, D. M., Jasieczek, C. B., Hannon, M. J., & Shooter, A. J. (1997) · Macromolecules · doi:10.1021/ma961074r · Cited by 394
Nickel-Mediated Living Radical Polymerization of Methyl Methacrylate
Uegaki, H., Kotani, Y., Kamigaito, M., & Sawamoto, M. (1997) · Macromolecules · doi:10.1021/ma961367k · Cited by 299
"Living" radical polymerization. 1. Possibilities and limitations
Greszta, D., Mardare, D., & Matyjaszewski, K. (1994) · Macromolecules · doi:10.1021/ma00081a002 · Cited by 260
Self-citationGrimaud, T., & Matyjaszewski, K. (1997) · Macromolecules · doi:10.1021/ma961796i · Cited by 234
Self-citation
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Self-citationKinetics of living radical polymerization
Goto, A., & Fukuda, T. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.01.002 · Cited by 914
Controlled/living radical polymerization
Matyjaszewski, K., & Spanswick, J. (2005) · Materials Today · doi:10.1016/s1369-7021(05)00745-5 · Cited by 746
Self-citationMorandi, G., Heath, L., & Thielemans, W. (2009) · Langmuir · doi:10.1021/la900452a · Cited by 405
Arget atrp of methyl methacrylate in the presence of nitrogen-based ligands as reducing agents
Kwak, Y., & Matyjaszewski, K. (2009) · Polymer International · doi:10.1002/pi.2530 · Cited by 159
Self-citation
Metadata
- Authors
- Xia, J., & Matyjaszewski, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-12-01
- Volume
- 30
- Issue
- 25
- Pages
- 7697-7700
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2080837087
- Cited by
- 455
- References
- 13
- FWCI
- 17.01
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
