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Cited by 927

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Controlled Synthesis of Polymer Brushes by “Living” Free Radical Polymerization Techniques

Husseman, Marc, Malmström, Eva E., McNamara, Molly, Mate, Mathew, Mecerreyes, David, Benoit, Didier G., Hedrick, James L., Mansky, Paul, Huang, E., Russell, Thomas P., Hawker, Craig J.·1999·Macromolecules
DOI 10.1021/ma981290v
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Abstract

The preparation of a wide variety of unique polymer brush structures can be accomplished by “living” free radical polymerization of vinyl monomers from surface-tethered alkoxyamines or from tethered α-halo esters in the presence of (PPh 3 ) 2 NiBr 2 . The use of a “living” free radical process permits the molecular weight and polydispersity of the covalently attached polymer chains to be accurately controlled while also allowing the formation of block copolymers by the sequential growth of monomers from the surface. These block and random copolymer brushes have been used to control surface properties.

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Research works printed but not linked: 19

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Metadata

Authors
Husseman, M., Malmström, E. E., McNamara, M., Mate, M., Mecerreyes, D., Benoit, D. G., Hedrick, J. L., Mansky, P., Huang, E., Russell, T. P., & Hawker, C. J.
Venue
Macromolecules
Publisher
American Chemical Society (ACS)
Published
1999-02-04
Volume
32
Issue
5
Pages
1424-1431
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
DOI
10.1021/ma981290v
OpenAlex
W1984633927
Cited by
927
References
0
FWCI
32.86
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Controlled Synthesis of Polymer Brushes by “Living” Free Radical Polymerization Techniques. https://app.cochat.ai/papers/10.1021/ma981290v
The paper
Husseman, M., Malmström, E. E., McNamara, M., Mate, M., Mecerreyes, D., Benoit, D. G., Hedrick, J. L., Mansky, P., Huang, E., Russell, T. P., & Hawker, C. J. (1999). Controlled Synthesis of Polymer Brushes by “Living” Free Radical Polymerization Techniques. Macromolecules. https://doi.org/10.1021/ma981290v

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.