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Large-Scale Alignment of ABC Block Copolymer Microdomains via Solvent Vapor Treatment
Abstract
We have studied the microdomain morphology of thin ABC triblock copolymer films supported by a solid substrate. The films were exposed to various solvent vapors, and the effect of the solvent removal speed on the resulting morphologies is investigated. Slow solvent extraction rates lead to a parallel alignment of lamellar microphases within the plane of the film. On fast drying, a perpendicular orientation of the lamellae is found. In the case of block copolymer samples with a highly anisotropic macroscopic shape, the microdomains can be aligned over large lateral areas. The results are discussed in view of the mechanical strain fields present during the drying process.
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Citations
Cites
Honeker, C. C., & Thomas, E. L. (1996) · Chemistry of Materials · doi:10.1021/cm960146q · Cited by 253
Cited by
Directing the self-assembly of block copolymers
Darling, S. B. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.05.004 · Cited by 1,019
Solvent Vapor Annealing of Block Polymer Thin Films
Sinturel, C., Vayer, M., Morris, M., & Hillmyer, M. A. (2013) · Macromolecules · doi:10.1021/ma400735a · Cited by 543
Arnal, M. L., Balsamo, V., López-Carrasquero, F., Contreras, J., Carrillo, M., Schmalz, H., Abetz, V., Laredo, E., & Müller, A. J. (2001) · Macromolecules · doi:10.1021/ma011058g · Cited by 87
Block Copolymers, Ternary Triblocks
Abetz, V. (2003) · Encyclopedia of Polymer Science and Technology · doi:10.1002/0471440264.pst423 · Cited by 9
Metadata
- Authors
- Fukunaga, K., Elbs, H., Magerle, R., & Krausch, G.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-01-19
- Volume
- 33
- Issue
- 3
- Pages
- 947-953
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1967316999
- Cited by
- 225
- References
- 1
- FWCI
- 3.68
- Type
- journal article
- Language
- en
- Open access
- closed
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