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“Living” Free Radical Photopolymerization Initiated from Surface-Grafted Iniferter Monolayers
Open accessAbstract
A method for chemically modifying a surface with grafted monolayers of initiator groups, which can be used for a “living” free radical photopolymerization, is described. By using “living” free radical polymerizations, we were able to control the length of the grafted polymer chains and therefore the layer thickness up to ∼100 nm. Also, single-layer grafted block copolymers were obtained by subsequent polymerizations of styrene and methyl methacrylate monomers. The surface-grafted polymer and block copolymer layers were evidenced by direct imaging methods (transmission and scanning electron microscopy) and by indirect surface characterization methods (contact angle measurements, SFM, XPS, and IR). The ability to control the thickness of the grafted polymer as well as the synthesis of a grafted block copolymer layer in a well-defined manner affirms the “living” character of the surface-initiated free radical photopolymerization.
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Cited by
Barbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
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Zhao, B., & Brittain, W. J. (2000) · Progress in Polymer Science · doi:10.1016/s0079-6700(00)00012-5 · Cited by 1,628
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
Chen, M., Zhong, M., & Johnson, J. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00671 · Cited by 1,202
Zoppe, J. O., Ataman, N. C., Mocny, P., Wang, J., Moraes, J., & Klok, H.-A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00314 · Cited by 1,046
Senaratne, W., Andruzzi, L., & Ober, C. K. (2005) · Biomacromolecules · doi:10.1021/bm050180a · Cited by 695
Tsujii, Y., Ohno, K., Yamamoto, S., Goto, A., & Fukuda, T. (2006) · Advances in Polymer Science · doi:10.1007/12_063 · Cited by 621
von Werne, T., & Patten, T. E. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010235q · Cited by 579
Tsujii, Y., Ejaz, M., Sato, K., Goto, A., & Fukuda, T. (2001) · Macromolecules · doi:10.1021/ma010733j · Cited by 310
Huang, W., Kim, J.-B., Bruening, M. L., & Baker, G. L. (2002) · Macromolecules · doi:10.1021/ma011159e · Cited by 276
Li, A., Benetti, E. M., Tranchida, D., Clasohm, J. N., Schönherr, H., & Spencer, N. D. (2011) · Macromolecules · doi:10.1021/ma2006443 · Cited by 113
Metadata
- Authors
- de Boer, B., Simon, H. K., Werts, M. P. L., van der Vegte, E. W., & Hadziioannou, G.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-12-29
- Volume
- 33
- Issue
- 2
- Pages
- 349-356
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2000960753
- Cited by
- 213
- References
- 0
- FWCI
- 7.98
- Type
- journal article
- Language
- en
- Open access
- green
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