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Solution Behavior of Poly(styrene)-block-poly(2-vinylpyridine) Micelles Containing Gold Nanoparticles
Abstract
Formation and structural transformation of inverse poly(styrene)- block -poly(2-vinylpyridine) micelles whose polyvinylpyridine core was loaded with HAuCl 4 or with elementary gold nanoclusters was studied by combined static and dynamic light scattering. A transformation in the morphology from spherical particles (small R g / R h ratio) to large anisomeric objects (large R g / R h ratio) was observed by decreasing the concentration of the block copolymer below the critical micelle concentration. At this point, the polymer chains are molecularly dispersed and no longer able to prevent uncontrolled growth of the gold nanoclusters.
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Citations
Cites
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Cited by
Daniel, M.-C., & Astruc, D. (2004) · Chemical Reviews · doi:10.1021/cr030698+ · Cited by 12,446
Gold Nanoparticles in Chemical and Biological Sensing
Saha, K., Agasti, S. S., Kim, C., Li, X., & Rotello, V. M. (2012) · Chemical Reviews · doi:10.1021/cr2001178 · Cited by 4,620
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Thermosensitive Gold Nanoparticles
Zhu, M.-Q., Wang, L.-Q., Exarhos, G. J., & Li, A. D. Q. (2004) · Journal of the American Chemical Society · doi:10.1021/ja038544z · Cited by 437
Recent advances in polymer protected gold nanoparticles: synthesis, properties and applications
Shan, J., & Tenhu, H. (2007) · Chemical Communications · doi:10.1039/b707740h · Cited by 411
Zhang, L., Yu, J. C., Yip, H. Y., Li, Q., Kwong, K. W., Xu, A.-W., & Wong, P. K. (2003) · Langmuir · doi:10.1021/la035330m · Cited by 296
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Metadata
- Authors
- Mössmer, S., Spatz, J. P., Möller, M., Aberle, T., Schmidt, J., & Burchard, W.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-06-01
- Volume
- 33
- Issue
- 13
- Pages
- 4791-4798
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2000235108
- Cited by
- 190
- References
- 2
- FWCI
- 8.71
- Type
- journal article
- Language
- en
- Open access
- closed
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