The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Seeded Semibatch Emulsion Polymerization of n-Butyl Acrylate. Kinetics and Structural Properties
Abstract
The seeded semibatch emulsion polymerization of n -butyl acrylate was investigated using potassium persulfate as initiator at 75 °C. The effect of initiator concentration and monomer feeding time (feed flow rate) on the kinetics, fraction of gel, molecular weight distributions, and level of branches were studied. It was found that the amount of gel formed was independent of initiator concentration and monomer feed flow rate if the process proceeded under starved conditions. On the other hand, the higher the initiator concentration and the feeding times, the higher the level of branches but the lower the molecular weights. A high level of branches was found, which was attributed to intramolecular transfer to polymer or backbiting.
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Citations
Cites
Odian, G. (2004) · doi:10.1002/047147875x · Cited by 7,158
Cited by
Catalytic Chain Transfer in Free-Radical Polymerizations
Gridnev, A. A., & Ittel, S. D. (2001) · Chemical Reviews · doi:10.1021/cr9901236 · Cited by 393
Metadata
- Authors
- Plessis, C., Arzamendi, G., Leiza, J. R., Schoonbrood, H. A. S., Charmot, D., & Asua, J. M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-06-23
- Volume
- 33
- Issue
- 14
- Pages
- 5041-5047
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2038653222
- Cited by
- 171
- References
- 1
- FWCI
- 5.23
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
