The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Complex Formation of Poly(ε-caprolactone) with Cyclodextrins
Abstract
Cyclodextrins (CDs) have been found to form inclusion complexes with poly(ε-caprolactone) (PEC) to give crystalline compounds. α- and γ-CD formed complexes with these polyesters in high yields, although β-CD gave complexes in moderate yields. The yields of the complexes decreased with increasing molecular weight of the polymer. α-CD−PEC complexes are stoichiometric one-to-one (cyclodextrin:monomer unit) compounds, and γ-CD−PEC complexes are one-to-two compounds when the molecular weights of PEC are low. The complexes were isolated and characterized by 1 H NMR, 13 C CP/MAS NMR, and X-ray diffraction studies. The inclusion modes are discussed.
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Cites
Crystal structure of poly(iε-caprolactone)
Hu, H., & Dorset, D. L. (1990) · Macromolecules · doi:10.1021/ma00223a017 · Cited by 225
Cited by
Cyclodextrin Rotaxanes and Polyrotaxanes
Wenz, G., Han, B.-H., & Müller, A. (2006) · Chemical Reviews · doi:10.1021/cr970027+ · Cited by 1,243
Harada, A., Hashidzume, A., Yamaguchi, H., & Takashima, Y. (2009) · Chemical Reviews · doi:10.1021/cr9000622 · Cited by 892
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Metadata
- Authors
- Kawaguchi, Y., Nishiyama, T., Okada, M., Kamachi, M., & Harada, A.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-05-26
- Volume
- 33
- Issue
- 12
- Pages
- 4472-4477
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2066087023
- Cited by
- 162
- References
- 1
- FWCI
- 5.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kawaguchi, Y., Nishiyama, T., Okada, M., Kamachi, M., & Harada, A. (2000). Complex Formation of Poly(ε-caprolactone) with Cyclodextrins. Macromolecules. https://doi.org/10.1021/ma992103b
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