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Ultrafine Cellulose Nanofibers as Efficient Adsorbents for Removal of UO22+ in Water
Abstract
Ultrafine cellulose nanofibers, 5–10 nm in diameter, were prepared from oxidation of wood pulp using the (2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO)/NaBr/NaClO process followed by mechanical treatment. Carboxylate groups on the surface of these nanofibers provide negative charges, which are very effective to adsorb radioactive UO 2 2+ in water, evidenced by static adsorption and high resolution transmission electron microscopy (TEM) measurements. The UO 2 2+ adsorption capability of ultrafine cellulose nanofibers was about 167 mg/g, which is 2–3 times higher than those of typical adsorbents such as montmorillonite, ion imprinted polymer particles, modified silica particles/fibrous membranes, and hydrogels. The high UO 2 2+ adsorption capability can be attributed to the very high surface-to-volume ratio, high surface charge density, and hydrophilicity of ultrafine cellulose nanofibers, which can be used as effective media to remove radioactive metals from radio-nuclear wastewater.
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Metadata
- Authors
- Ma, H., Hsiao, B. S., & Chu, B.
- Venue
- ACS Macro Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-12-22
- Volume
- 1
- Issue
- 1
- Pages
- 213-216
- ISSN
- 2161-1653 (ISSN-L)
- OpenAlex
- W2322719178
- Cited by
- 213
- References
- 2
- FWCI
- 4.05
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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