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Nanotubes Prepared by Templating Sacrificial Nickel Nanorods
Abstract
We present a versatile method, based on the electrostatic self-assembly of oppositely charged species onto sacrificial templates, for the preparation of nanotubes. Polymer and polymer composite nanotubes were prepared by the layer-by-layer (LbL) deposition of polyelectrolytes and/or a charged inorganic molecular precursor onto nickel nanorods, followed by removal of the core by dissolution. Surface charge reversal of the nanotubes was observed at the end of each deposition step, which facilitated the multilayer buildup. The precursor core−shell nanorods prepared and the resulting nanotubes obtained upon dissolution of the core were characterized using transmission electron microscopy. The LbL approach is facile, adaptable, and able to be performed from aqueous-based solutions, thereby opening new avenues for the preparation of a broad range of nanotubes with tailored composition and wall thickness.
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Citations
Cited by
One‐Dimensional Nanostructures: Synthesis, Characterization, and Applications
Xia, Y., Yang, P., Sun, Y., Wu, Y., Mayers, B., Gates, B., Yin, Y., Kim, F., & Yan, H. (2003) · Advanced Materials · doi:10.1002/adma.200390087 · Cited by 8,559
Ariga, K., Hill, J. P., & Ji, Q. (2007) · Physical Chemistry Chemical Physics · doi:10.1039/b700410a · Cited by 1,256
Template Synthesis of Nanostructured Materials via Layer-by-Layer Assembly
Wang, Y., Angelatos, A. S., & Caruso, F. (2008) · Chemistry of Materials · doi:10.1021/cm7024813 · Cited by 767
Self-citationThe Synthesis and Fabrication of One‐Dimensional Nanoscale Heterojunctions
Mieszawska, A. J., Jalilian, R., Sumanasekera, G. U., & Zamborini, F. P. (2007) · Small · doi:10.1002/smll.200600727 · Cited by 288
Nanowire-in-Microtube Structured Core/Shell Fibers via Multifluidic Coaxial Electrospinning
Chen, H., Wang, N., Di, J., Zhao, Y., Song, Y., & Jiang, L. (2010) · Langmuir · doi:10.1021/la100611f · Cited by 287
The Assembly of Coated Nanocrystals
Liz-Marzán, L. M., & Mulvaney, P. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp027835b · Cited by 278
Qian, H.-S., Yu, S.-H., Luo, L.-B., Gong, J.-Y., Fei, L.-F., & Liu, X.-M. (2006) · Chemistry of Materials · doi:10.1021/cm052848y · Cited by 263
Metadata
- Authors
- Mayya, K. S., Gittins, D. I., Dibaj, A. M., & Caruso, F.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-10-27
- Volume
- 1
- Issue
- 12
- Pages
- 727-730
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2033419660
- Cited by
- 164
- References
- 0
- FWCI
- 7.28
- Type
- journal article
- Language
- en
- Open access
- closed
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