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Effect of Surface Passivation on the Electrogenerated Chemiluminescence of CdSe/ZnSe Nanocrystals
Abstract
The electrogenerated chemiluminescence (ECL) spectrum of CdSe/ZnSe nanocrystals (NCs) dispersed in a CH 2 Cl 2 solution containing 0.1 M TBAP was obtained by stepping the potential between +2.3 and −2.3 V. Unlike the spectra from the ECL of Si or CdSe NCs, where the emission occurs in a single peak that is significantly red-shifted from the photoluminescence (PL) peak (attributed to emission from surface states), ECL from CdSe/ZnSe produced a spectrum containing two peaks: a sharp peak whose position was almost identical to that in the PL spectrum and another broader peak with a red shift of ∼200 nm compared to that in the PL. This suggests emission from both surface states on the NCs and from the bulk in NCs where the surface states have been passivated.
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Cites
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
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Baker, S. N., & Baker, G. A. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200906623 · Cited by 4,921
Zheng, L., Chi, Y., Dong, Y., Lin, J., & Wang, B. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809073f · Cited by 907
A Facile Microwave Avenue to Electrochemiluminescent Two‐Color Graphene Quantum Dots
Li, L., Ji, J., Fei, R., Wang, C., Lu, Q., Zhang, J., Jiang, L., & Zhu, J. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201200166 · Cited by 890
Polyamine-functionalized carbon quantum dots for chemical sensing
Dong, Y., Wang, R., Li, H., Shao, J., Chi, Y., Lin, X., & Chen, G. (2012) · Carbon · doi:10.1016/j.carbon.2012.02.046 · Cited by 623
Extraction of Electrochemiluminescent Oxidized Carbon Quantum Dots from Activated Carbon
Dong, Y., Zhou, N., Lin, X., Lin, J., Chi, Y., & Chen, G. (2010) · Chemistry of Materials · doi:10.1021/cm1018844 · Cited by 422
Metadata
- Authors
- Myung, N., Bae, Y., & Bard, A. J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-07-23
- Volume
- 3
- Issue
- 8
- Pages
- 1053-1055
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2101027063
- Cited by
- 316
- References
- 1
- FWCI
- 3.39
- Type
- journal article
- Language
- en
- Open access
- closed
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