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Dependence of Optical Transition Energies on Structure for Single-Walled Carbon Nanotubes in Aqueous Suspension: An Empirical Kataura Plot
Abstract
Spectrofluorimetric data for identified single-walled carbon nanotubes in aqueous SDS suspension have been accurately fit to empirical expressions. These are used to obtain the first model-independent prediction of first and second van Hove optical transitions as a function of structure for a wide range of semiconducting nanotubes. To allow for convenient use in support of spectral studies, the results are presented in equation, graphical, and tabular forms. These empirical findings differ significantly from Kataura plots computed using a simple tight-binding model. It is suggested that the empirically based results should be used in preference to conventional model-based predictions in spectroscopic nanotube research.
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Citations
Cited by
Theory of Electronic States and Transport in Carbon Nanotubes
Ando, T. (2005) · Journal of the Physical Society of Japan · doi:10.1143/jpsj.74.777 · Cited by 893
Quasi-ballistic carbon nanotube array transistors with current density exceeding Si and GaAs
Brady, G. J., Way, A. J., Safron, N. S., Evensen, H. T., Gopalan, P., & Arnold, M. S. (2016) · Science Advances · doi:10.1126/sciadv.1601240 · Cited by 359
Generation of Terahertz Radiation by Optical Excitation of Aligned Carbon Nanotubes
Titova, L. V., Pint, C. L., Zhang, Q., Hauge, R. H., Kono, J., & Hegmann, F. A. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b00494 · Cited by 102
Metadata
- Authors
- Weisman, R. B., & Bachilo, S. M.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-08-08
- Volume
- 3
- Issue
- 9
- Pages
- 1235-1238
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2144458599
- Cited by
- 1,187
- References
- 0
- FWCI
- 23.95
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Dependence of Optical Transition Energies on Structure for Single-Walled Carbon Nanotubes in Aqueous Suspension: An Empirical Kataura Plot. https://app.cochat.ai/papers/10.1021/nl034428i
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- Weisman, R. B., & Bachilo, S. M. (2003). Dependence of Optical Transition Energies on Structure for Single-Walled Carbon Nanotubes in Aqueous Suspension: An Empirical Kataura Plot. Nano Letters. https://doi.org/10.1021/nl034428i
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