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High-Density Silver Nanoparticle Film with Temperature-Controllable Interparticle Spacing for a Tunable Surface Enhanced Raman Scattering Substrate
Abstract
The formation of high-density silver nanoparticles and a novel method to precisely control the spacing between nanoparticles by temperature are demonstrated for a tunable surface enhanced Raman scattering substrates. The high-density nanoparticle thin film is accomplished by self-assembling through the Langmuir-Blodgett (LB) technique on a water surface and transferring the particle monolayer to a temperature-responsive polymer membrane. The temperature-responsive polymer membrane allows producing a dynamic surface enhanced Raman scattering substrate. The plasmon peak of the silver nanoparticle film red shifts up to 110 nm with increasing temperature. The high-density particle film serves as an excellent substrate for surface-enhanced Raman spectroscopy (SERS), and the scattering signal enhancement factor can be dynamically tuned by the thermally activated SERS substrate. The SERS spectra of Rhodamine 6G on a high-density silver particle film at various temperatures is characterized to demonstrate the tunable plasmon coupling between high-density nanoparticles.
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Cites
Optical Constants of the Noble Metals
Johnson, P. B., & Christy, R. W. (1972) · Physical Review B · doi:10.1103/physrevb.6.4370 · Cited by 20,094
Cited by
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
Challenges and breakthroughs in recent research on self-assembly
Ariga, K., Hill, J. P., Lee, M. V., Vinu, A., Charvet, R., & Acharya, S. (2008) · Science and Technology of Advanced Materials · doi:10.1088/1468-6996/9/1/014109 · Cited by 759
Highly Raman‐Enhancing Substrates Based on Silver Nanoparticle Arrays with Tunable Sub‐10 nm Gaps
Wang, H. ‐., Liu, C. ‐., Wu, S. ‐., Liu, N. ‐., Peng, C. ‐., Chan, T. ‐., Hsu, C. ‐., Wang, J. ‐., & Wang, Y. ‐. (2006) · Advanced Materials · doi:10.1002/adma.200501875 · Cited by 478
Guerrini, L., & Graham, D. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35118h · Cited by 441
Present and future of metal nanoparticles in tumor ablation therapy
Lou, W., Xie, L., Xu, L., Xu, M., Xu, F., Zhao, Q., & Jiang, T. (2023) · Nanoscale · doi:10.1039/d3nr04362b · Cited by 33
Metadata
- Authors
- Lu, Y., Liu, G. L., & Lee, L. P.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-12-16
- Volume
- 5
- Issue
- 1
- Pages
- 5-9
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2020206672
- Cited by
- 589
- References
- 1
- FWCI
- 15.43
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: High-Density Silver Nanoparticle Film with Temperature-Controllable Interparticle Spacing for a Tunable Surface Enhanced Raman Scattering Substrate. https://app.cochat.ai/papers/10.1021/nl048965u
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- Lu, Y., Liu, G. L., & Lee, L. P. (2005). High-Density Silver Nanoparticle Film with Temperature-Controllable Interparticle Spacing for a Tunable Surface Enhanced Raman Scattering Substrate. Nano Letters. https://doi.org/10.1021/nl048965u
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.