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Raman Scattering from High-Frequency Phonons in Supported n-Graphene Layer Films

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Gupta, A., Chen, G., Joshi, P., Tadigadapa, S., Eklund·2006·Nano Letters

Abstract

Results of room-temperature Raman scattering studies of ultrathin graphitic films supported on Si (100)/SiO2 substrates are reported. The results are significantly different from those known for graphite. Spectra were collected using 514.5 nm radiation on films containing from n = 1 to 20 graphene layers, as determined by atomic force microscopy. Both the first- and second-order Raman spectra show unique signatures of the number of layers in the film. The nGL film analogue of the Raman G-band in graphite exhibits a Lorentzian line shape whose center frequency shifts linearly relative to graphite as approximately 1/n (for n = 1 omegaG approximately 1587 cm-1). Three weak bands, identified with disorder-induced first-order scattering, are observed at approximately 1350, 1450, and 1500 cm-1. The approximately 1500 cm-1 band is weak but relatively sharp and exhibits an interesting n-dependence. In general, the intensity of these D-bands decreases dramatically with increasing n. Three second-order bands are also observed (approximately 2450, approximately 2700, and 3248 cm-1). They are analogues to those observed in graphite. However, the approximately 2700 cm-1 band exhibits an interesting and dramatic change of shape with n. Interestingly, for n < 5 this second-order band is more intense than the G-band.

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Metadata

Authors
Gupta, A., Chen, G., Joshi, P., Tadigadapa, S., & Eklund
Venue
Nano Letters
Published
2006-11-16
Volume
6
Issue
12
Pages
2667-2673
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2081362853
Cited by
1,475
References
6
FWCI
29.73
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Raman Scattering from High-Frequency Phonons in Supported n-Graphene Layer Films. https://app.cochat.ai/papers/10.1021/nl061420a
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Gupta, A., Chen, G., Joshi, P., Tadigadapa, S., & Eklund. (2006). Raman Scattering from High-Frequency Phonons in Supported n-Graphene Layer Films. Nano Letters. https://doi.org/10.1021/nl061420a

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