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Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO2 Molecules
Abstract
Crystal-to-crystal transformation from a 3D interpenetrated-type MOF {[Cu(BF(4))(2)(bpy)(H(2)O)(2)] (bpy)} (1) to a 2D square-grid-type [Cu(BF(4))(2)(bpy)(2)] (2) (bpy = 4,4'-bipyridine) was observed. It was derived from dehydration and confirmed by in situ FT-IR, TG, and elemental analysis. Moreover, we elucidate the novel expansion/shrinkage dynamic modulation of 2 triggered by clathrate formation with gas molecules.
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Citations
Cited by
Furukawa, H., & Yaghi, O. M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9015765 · Cited by 2,608
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Linker functionalized metal-organic frameworks
Ali Akbar Razavi, S., & Morsali, A. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.213023 · Cited by 341
Ionic metal-organic frameworks (iMOFs): Design principles and applications
Karmakar, A., Desai, A. V., & Ghosh, S. K. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.08.007 · Cited by 308
Entangled Two-Dimensional Coordination Networks: A General Survey
Carlucci, L., Ciani, G., Proserpio, D. M., Mitina, T. G., & Blatov, V. A. (2014) · Chemical Reviews · doi:10.1021/cr500150m · Cited by 285
Metadata
- Authors
- Kondo, A., Noguchi, H., Ohnishi, S., Kajiro, H., Tohdoh, A., Hattori, Y., Xu, W.-C., Tanaka, H., Kanoh, H., & Kaneko, K.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-10-25
- Volume
- 6
- Issue
- 11
- Pages
- 2581-2584
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2002880500
- Cited by
- 286
- References
- 0
- FWCI
- 10.16
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO2 Molecules. https://app.cochat.ai/papers/10.1021/nl062032b
- The paper
- Kondo, A., Noguchi, H., Ohnishi, S., Kajiro, H., Tohdoh, A., Hattori, Y., Xu, W.-C., Tanaka, H., Kanoh, H., & Kaneko, K. (2006). Novel Expansion/Shrinkage Modulation of 2D Layered MOF Triggered by Clathrate Formation with CO2 Molecules. Nano Letters. https://doi.org/10.1021/nl062032b
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