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Ultralow Feeding Gas Flow Guiding Growth of Large-Scale Horizontally Aligned Single-Walled Carbon Nanotube Arrays

Jin, Zhong, Chu, Haibin, Wang, Jinyong, Hong, Jinxing, Tan, Wenchang, Li, Yan·2007·Nano Letters

Abstract

On the basis of the rational analysis about the fluidic property of the system, an ultralow gas flow chemical vapor deposition (CVD) strategy was designed to prepare large-scale horizontally aligned ultralong single-walled carbon nanotube (SWNT) arrays. SWNT arrays could be well obtained under extremely low feeding flow of 1.5 sccm in a 1 in. quartz tube reactor. It was confirmed that the tubes grew floatingly and could cross microtrenches or climb over micro-obstacles in ultraslow gas flow. SWNTs arrays also could be formed no matter the substrate was placed vertically or upside down. The growth mechanism was discussed. Both the buoyancy effect induced by gas temperature/density difference and gas flow stability played dominant roles. More attractively, simultaneous batch-scale preparation of SWNT arrays was realized by the ultralow gas flow strategy. This new strategy turns to be more abstemious, efficient, promising, and flexible compared with the high gas flow rate fast-heating CVD processes.

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Authors
Jin, Z., Chu, H., Wang, J., Hong, J., Tan, W., & Li, Y.
Venue
Nano Letters
Published
2007-06-08
Volume
7
Issue
7
Pages
2073-2079
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2127905811
Cited by
222
References
0
FWCI
10.24
Type
journal article
Language
en
Open access
closed

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