The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Increased Water Retention in Polymer Electrolyte Membranes at Elevated Temperatures Assisted by Capillary Condensation
Abstract
We establish a new systematic methodology for controlling the water retention of polymer electrolyte membranes. Block copolymer membranes comprising hydrophilic phases with widths ranging from 2 to 5 nm become wetter as the temperature of the surrounding air is increased at constant relative humidity. The widths of the moist hydrophilic phases were measured by cryogenic electron microscopy experiments performed on humid membranes. Simple calculations suggest that capillary condensation is important at these length scales. The correlation between moisture content and proton conductivity of the membranes is demonstrated.
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Citations
Cites
Kreuer, K.-D., Paddison, S. J., Spohr, E., & Schuster, M. (2004) · Chemical Reviews · doi:10.1021/cr020715f · Cited by 2,187
Water Uptake of Perfluorosulfonic Acid Membranes from Liquid Water and Water Vapor
Hinatsu, J. T., Mizuhata, M., & Takenaka, H. (1994) · Journal of The Electrochemical Society · doi:10.1149/1.2054951 · Cited by 518
Jiang, R., Kunz, H. R., & Fenton, J. M. (2005) · Journal of Power Sources · doi:10.1016/j.jpowsour.2005.03.180 · Cited by 164
Cited by
New Insights into Perfluorinated Sulfonic-Acid Ionomers
Kusoglu, A., & Weber, A. Z. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00159 · Cited by 2,432
Self-citationRecent Development of Polymer Electrolyte Membranes for Fuel Cells
Zhang, H., & Shen, P. K. (2012) · Chemical Reviews · doi:10.1021/cr200035s · Cited by 1,361
Hallinan, D. T., & Balsara, N. P. (2013) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-071312-121705 · Cited by 853
Self-citationStructure‐Morphology‐Property Relationships of Non‐Perfluorinated Proton‐Conducting Membranes
Peckham, T. J., & Holdcroft, S. (2010) · Advanced Materials · doi:10.1002/adma.201001164 · Cited by 622
Ion Transport by Nanochannels in Ion-Containing Aromatic Copolymers
Li, N., & Guiver, M. D. (2014) · Macromolecules · doi:10.1021/ma402254h · Cited by 440
Metadata
- Authors
- Park, M. J., Downing, K. H., Jackson, A., Gomez, E. D., Minor, A. M., Cookson, D., Weber, A. Z., & Balsara, N. P.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-10-26
- Volume
- 7
- Issue
- 11
- Pages
- 3547-3552
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2141128879
- Cited by
- 216
- References
- 3
- FWCI
- 12.29
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.