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Visible Light-Induced Charge Retention and Photocatalysis with Hybrid CdSe−Au Nanodumbbells
Abstract
Visible light photocatalysis is a promising route for harnessing of solar energy to perform useful chemical reactions and to convert light to chemical energy. Nanoscale photocatalytic systems used to date were based mostly on oxide semiconductors aided by metal deposition and were operational only under UV illumination. Additionally, the degree of control over particle size and shape was limited. We report visible light photocatalysis using highly controlled hybrid gold-tipped CdSe nanorods (nanodumbbells). Under visible light irradiation, charge separation takes place between the semiconductor and metal parts of the hybrid particles. The charge-separated state was then utilized for direct photoreduction of a model acceptor molecule, methylene blue, or alternatively, retained for later use to perform the reduction reaction in the dark.
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Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Cited by
Shahbazi, M.-A., Faghfouri, L., Ferreira, M. P. A., Figueiredo, P., Maleki, H., Sefat, F., Hirvonen, J., & Santos, H. A. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00283a · Cited by 523
Nanotechnology in Solar and Biofuels
Ramsurn, H., & Gupta, R. B. (2013) · ACS Sustainable Chemistry & Engineering · doi:10.1021/sc400046y · Cited by 109
Metadata
- Authors
- Costi, R., Saunders, A. E., Elmalem, E., Salant, A., & Banin, U.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-01-16
- Volume
- 8
- Issue
- 2
- Pages
- 637-641
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2041033082
- Cited by
- 478
- References
- 1
- FWCI
- 17.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Costi, R., Saunders, A. E., Elmalem, E., Salant, A., & Banin, U. (2008). Visible Light-Induced Charge Retention and Photocatalysis with Hybrid CdSe−Au Nanodumbbells. Nano Letters. https://doi.org/10.1021/nl0730514
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