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Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition
Abstract
Atomic layer deposition (ALD) is used to deposit ruthenium-platinum nanostructured catalysts using 2,4-(dimethylpentadienyl)(ethylcyclopentadienyl) ruthenium, trimethyl(methylcyclopentadienyl) platinum, and oxygen as precursors. Transmission electron microscopy shows discrete 1.2 nm nanoparticles decorating the surface of the spherical alumina support. The Ru-Pt particles are crystalline and have a crystal structure similar to pure platinum. X-ray fluorescence measurements show that the nanoparticle composition is controlled by the ratio of metal precursor ALD cycles. X-ray absorption spectroscopy at the Ru K-edge indicates a nearest neighbor Ru-Pt interaction consistent with a bimetallic composition. Methanol decomposition reactions further confirm a Ru-Pt interaction and show enhanced methanol conversion for the bimetallic nanoparticles when compared to catalysts comprised of a mixture of pure Pt and Ru nanoparticles of similar loading. These results demonstrate that ALD is a viable technique for synthesizing mixed-metal nanostructures suitable for catalysis and other applications.
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Cited by
Recent Developments in the Synthesis of Supported Catalysts
Munnik, P., de Jongh, P. E., & de Jong, K. P. (2015) · Chemical Reviews · doi:10.1021/cr500486u · Cited by 1,528
Synergistic Catalysis over Bimetallic Alloy Nanoparticles
Singh, A. K., & Xu, Q. (2013) · ChemCatChem · doi:10.1002/cctc.201200591 · Cited by 698
Nanocatalysis: size- and shape-dependent chemisorption and catalytic reactivity
Roldan Cuenya, B., & Behafarid, F. (2015) · Surface Science Reports · doi:10.1016/j.surfrep.2015.01.001 · Cited by 388
Tailoring nanoporous materials by atomic layer deposition
Detavernier, C., Dendooven, J., Pulinthanathu Sree, S., Ludwig, K. F., & Martens, J. A. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15091j · Cited by 386
Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition
Lu, J., Elam, J. W., & Stair, P. C. (2013) · Accounts of Chemical Research · doi:10.1021/ar300229c · Cited by 329
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Metadata
- Authors
- Christensen, S. T., Feng, H., Libera, J. L., Guo, N., Miller, J. T., Stair, P. C., & Elam, J. W.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-07-12
- Volume
- 10
- Issue
- 8
- Pages
- 3047-3051
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2019902311
- Cited by
- 219
- References
- 0
- FWCI
- 8.65
- Type
- journal article
- Language
- en
- Open access
- closed
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- Christensen, S. T., Feng, H., Libera, J. L., Guo, N., Miller, J. T., Stair, P. C., & Elam, J. W. (2010). Supported Ru−Pt Bimetallic Nanoparticle Catalysts Prepared by Atomic Layer Deposition. Nano Letters. https://doi.org/10.1021/nl101567m
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