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Derivitization of Pristine Graphene with Well-Defined Chemical Functionalities
Open accessAbstract
Covalent functionalization of pristine graphene poses considerable challenges due to the lack of reactive functional groups. Herein, we report a simple and general method to covalently functionalize pristine graphene with well-defined chemical functionalities. It is a solution-based process where solvent-exfoliated graphene was treated with perfluorophenylazide (PFPA) by photochemical or thermal activation. Graphene with well-defined functionalities was synthesized, and the resulting materials were soluble in organic solvents or water depending on the nature of the functional group on PFPA.
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Cites
The chemistry of graphene oxide
Dreyer, D. R., Park, S., Bielawski, C. W., & Ruoff, R. S. (2010) · Chem. Soc. Rev. · doi:10.1039/b917103g · Cited by 11,653
Cited by
Georgakilas, V., Perman, J. A., Tucek, J., & Zboril, R. (2015) · Chemical Reviews · doi:10.1021/cr500304f · Cited by 2,147
Biological and chemical sensors based on graphene materials
Liu, Y., Dong, X., & Chen, P. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15270j · Cited by 1,748
Chang, H., & Wu, H. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42518e · Cited by 549
Chemical functionalization and characterization of graphene-based materials
Bottari, G., Herranz, M. Á., Wibmer, L., Volland, M., Rodríguez-Pérez, L., Guldi, D. M., Hirsch, A., Martín, N., D'Souza, F., & Torres, T. (2017) · Chemical Society Reviews · doi:10.1039/c7cs00229g · Cited by 441
Organic Functionalization of Graphene in Dispersions
Quintana, M., Vazquez, E., & Prato, M. (2013) · Accounts of Chemical Research · doi:10.1021/ar300138e · Cited by 240
Metadata
- Authors
- Liu, L.-H., Lerner, M. M., & Yan, M.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-08-06
- Volume
- 10
- Issue
- 9
- Pages
- 3754-3756
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2043360724
- Cited by
- 190
- References
- 1
- FWCI
- 9.58
- Type
- journal article
- Language
- en
- Open access
- green
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
