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Vertically Aligned WO3 Nanowire Arrays Grown Directly on Transparent Conducting Oxide Coated Glass: Synthesis and Photoelectrochemical Properties
Abstract
Photocorrosion stable WO(3) nanowire arrays are synthesized by a solvothermal technique on fluorine-doped tin oxide coated glass. WO(3) morphologies of hexagonal and monoclinic structure, ranging from nanowire to nanoflake arrays, are tailored by adjusting solution composition with growth along the (001) direction. Photoelectrochemical measurements of illustrative films show incident photon-to-current conversion efficiencies higher than 60% at 400 nm with a photocurrent of 1.43 mA/cm(2) under AM 1.5G illumination. Our solvothermal film growth technique offers an exciting opportunity for growth of one-dimensional metal oxide nanostructures with practical application in photoelectrochemical energy conversion.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Growth of nanowire superlattice structures for nanoscale photonics and electronics
Gudiksen, M. S., Lauhon, L. J., Wang, J., Smith, D. C., & Lieber, C. M. (2002) · Nature · doi:10.1038/415617a · Cited by 2,709
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Low-dimensional catalysts for hydrogen evolution and CO2 reduction
Voiry, D., Shin, H. S., Loh, K. P., & Chhowalla, M. (2018) · Nature Reviews Chemistry · doi:10.1038/s41570-017-0105 · Cited by 848
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Wang, S., Liu, G., & Wang, L. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00584 · Cited by 847
Qiu, Y., Yan, K., Deng, H., & Yang, S. (2012) · Nano Letters · doi:10.1021/nl2037326 · Cited by 406
Wang, G., Ling, Y., & Li, Y. (2012) · Nanoscale · doi:10.1039/c2nr32222f · Cited by 377
Metadata
- Authors
- Su, J., Feng, X., Sloppy, J. D., Guo, L., & Grimes, C. A.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-11-29
- Volume
- 11
- Issue
- 1
- Pages
- 203-208
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1993305125
- Cited by
- 589
- References
- 2
- FWCI
- 25.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Su, J., Feng, X., Sloppy, J. D., Guo, L., & Grimes, C. A. (2011). Vertically Aligned WO3 Nanowire Arrays Grown Directly on Transparent Conducting Oxide Coated Glass: Synthesis and Photoelectrochemical Properties. Nano Letters. https://doi.org/10.1021/nl1034573
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