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Spindle-like Mesoporous α-Fe2O3 Anode Material Prepared from MOF Template for High-Rate Lithium Batteries
Abstract
Spindle-like porous α-Fe(2)O(3) was prepared from an iron-based metal organic framework (MOF) template. When tested as anode material for lithium batteries (LBs), this spindle-like porous α-Fe(2)O(3) shows greatly enhanced performance of Li storage. The particle with a length and width of ∼0.8 and ∼0.4 μm, respectively, was composed of clustered Fe(2)O(3) nanoparticles with sizes of <20 nm. The capacity of the porous α-Fe(2)O(3) retained 911 mAh g(-1) after 50 cycles at a rate of 0.2 C. Even when cycled at 10 C, comparable capacity of 424 mAh g(-1) could be achieved.
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Citations
Cited by
Wu, H. B., Xia, B. Y., Yu, L., Yu, X.-Y., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7512 · Cited by 1,434
Metal–organic frameworks as platforms for clean energy
Li, S.-L., & Xu, Q. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40507a · Cited by 970
Electrode Degradation in Lithium-Ion Batteries
Pender, J. P., Jha, G., Youn, D. H., Ziegler, J. M., Andoni, I., Choi, E. J., Heller, A., Dunn, B. S., Weiss, P. S., Penner, R. M., et al. (2020) · ACS Nano · doi:10.1021/acsnano.9b04365 · Cited by 873
Conversion Reaction‐Based Oxide Nanomaterials for Lithium Ion Battery Anodes
Yu, S., Lee, S. H., Lee, D. J., Sung, Y., & Hyeon, T. (2016) · Small · doi:10.1002/smll.201502299 · Cited by 499
Meng, T., Qin, J., Wang, S., Zhao, D., Mao, B., & Cao, M. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta01453h · Cited by 227
Metadata
- Authors
- Xu, X., Cao, R., Jeong, S., & Cho, J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-08-14
- Volume
- 12
- Issue
- 9
- Pages
- 4988-4991
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2133699671
- Cited by
- 914
- References
- 0
- FWCI
- 54.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, X., Cao, R., Jeong, S., & Cho, J. (2012). Spindle-like Mesoporous α-Fe2O3 Anode Material Prepared from MOF Template for High-Rate Lithium Batteries. Nano Letters. https://doi.org/10.1021/nl302618s
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