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Extraordinary Room-Temperature Photoluminescence in Triangular WS2 Monolayers

Open access
Gutiérrez, Humberto R., Perea-López, Nestor, Elías, Ana Laura, Berkdemir, Ayse, Wang, Bei, Lv, Ruitao, López-Urías, Florentino, Crespi, Vincent H., Terrones, Humberto, Terrones, Mauricio·2013·Nano Letters

Abstract

Individual monolayers of metal dichalcogenides are atomically thin two-dimensional crystals with attractive physical properties different from those of their bulk counterparts. Here we describe the direct synthesis of WS2 monolayers with triangular morphologies and strong room-temperature photoluminescence (PL). The Raman response as well as the luminescence as a function of the number of S-W-S layers is also reported. The PL weakens with increasing number of layers due to a transition from direct band gap in a monolayer to indirect gap in multilayers. The edges of WS2 monolayers exhibit PL signals with extraordinary intensity, around 25 times stronger than that at the platelet's center. The structure and chemical composition of the platelet edges appear to be critical for PL enhancement.

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Crossref · 10.1021/nl3026357

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Metadata

Authors
Gutiérrez, H. R., Perea-López, N., Elías, A. L., Berkdemir, A., Wang, B., Lv, R., López-Urías, F., Crespi, V. H., Terrones, H., & Terrones, M.
Venue
Nano Letters
Published
2012-12-14
Volume
13
Issue
8
Pages
3447-3454
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W1943833960
Cited by
1,603
References
5
FWCI
40.40
Type
journal article
Language
en
Open access
green

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