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Charge Density Waves in Exfoliated Films of van der Waals Materials: Evolution of Raman Spectrum in TiSe2
Abstract
A number of the charge-density-wave materials reveal a transition to the macroscopic quantum state around 200 K. We used graphene-like mechanical exfoliation of TiSe(2) crystals to prepare a set of films with different thicknesses. The transition temperature to the charge-density-wave state was determined via modification of Raman spectra of TiSe(2) films. It was established that the transition temperature can increase from its bulk value to ~240 K as the thickness of the van der Waals films reduces to the nanometer range. The obtained results are important for the proposed applications of such materials in the collective-state information processing, which require room-temperature operation.
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Cited by
Progress, Challenges, and Opportunities in Two-Dimensional Materials Beyond Graphene
Butler, S. Z., Hollen, S. M., Cao, L., Cui, Y., Gupta, J. A., Gutiérrez, H. R., Heinz, T. F., Hong, S. S., Huang, J., Ismach, A. F., et al. (2013) · ACS Nano · doi:10.1021/nn400280c · Cited by 4,878
Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2T x MXene
Sarycheva, A., & Gogotsi, Y. (2020) · Chemistry of Materials · doi:10.1021/acs.chemmater.0c00359 · Cited by 1,467
Metadata
- Authors
- Goli, P., Khan, J., Wickramaratne, D., Lake, R. K., & Balandin, A. A.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-10-25
- Volume
- 12
- Issue
- 11
- Pages
- 5941-5945
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2335244695
- Cited by
- 181
- References
- 0
- FWCI
- 5.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Charge Density Waves in Exfoliated Films of van der Waals Materials: Evolution of Raman Spectrum in TiSe2. https://app.cochat.ai/papers/10.1021/nl303365x
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- Goli, P., Khan, J., Wickramaratne, D., Lake, R. K., & Balandin, A. A. (2012). Charge Density Waves in Exfoliated Films of van der Waals Materials: Evolution of Raman Spectrum in TiSe2. Nano Letters. https://doi.org/10.1021/nl303365x
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