The DOI matches its Crossref record; 48 of the 48 references it cites were found in a registry or an index.
Hybrid Device Employing Three-Dimensional Arrays of MnO in Carbon Nanosheets Bridges Battery–Supercapacitor Divide
Abstract
It is a challenge to meld the energy of secondary batteries with the power of supercapacitors. Herein, we created electrodes finely tuned for this purpose, consisting of a monolayer of MnO nanocrystallites mechanically anchored by pore-surface terminations of 3D arrays of graphene-like carbon nanosheets ("3D-MnO/CNS"). The biomass-derived carbon nanosheets should offer a synthesis cost advantage over comparably performing designer nanocarbons, such as graphene or carbon nanotubes. High Li storage capacity is achieved by bulk conversion and intercalation reactions, while high rates are maintained through stable ∼20 nm scale diffusion distances. For example, 1332 mAh g(-1) is reached at 0.1 A g(-1), 567 mAh g(-1) at 5 A g(-1), and 285 mAh g(-1) at 20 A g(-1) with negligible degradation at 500 cycles. We employed 3D-MnO/CNS (anode) and carbon nanosheets (cathode) to create a hybrid capacitor displaying among the most promising performances reported: based on the active materials, it delivers 184 Wh kg(-1) at 83 W kg(-1) and 90 Wh kg(-1) at 15 000 W kg(-1) with 76% capacity retention after 5000 cycles.
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Cites
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Cited by
Battery‐Supercapacitor Hybrid Devices: Recent Progress and Future Prospects
Zuo, W., Li, R., Zhou, C., Li, Y., Xia, J., & Liu, J. (2017) · Advanced Science · doi:10.1002/advs.201600539 · Cited by 1,637
Wang, Q., Yan, J., & Fan, Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03109e · Cited by 1,225
Nonaqueous Hybrid Lithium‐Ion and Sodium‐Ion Capacitors
Wang, H., Zhu, C., Chao, D., Yan, Q., & Fan, H. J. (2017) · Advanced Materials · doi:10.1002/adma.201702093 · Cited by 870
Self-citationPeanut shell hybrid sodium ion capacitor with extreme energy–power rivals lithium ion capacitors
Ding, J., Wang, H., Li, Z., Cui, K., Karpuzov, D., Tan, X., Kohandehghan, A., & Mitlin, D. (2015) · Energy & Environmental Science · doi:10.1039/c4ee02986k · Cited by 818
Self-citationMetal oxide-based supercapacitors: progress and prospectives
An, C., Zhang, Y., Guo, H., & Wang, Y. (2019) · Nanoscale Advances · doi:10.1039/c9na00543a · Cited by 789
Metadata
- Authors
- Wang, H., Xu, Z., Li, Z., Cui, K., Ding, J., Kohandehghan, A., Tan, X., Zahiri, B., Olsen, B. C., Holt, C. M. B., & Mitlin, D.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-12
- Volume
- 14
- Issue
- 4
- Pages
- 1987-1994
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2319816086
- Cited by
- 299
- References
- 48
- FWCI
- 12.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wang, H., Xu, Z., Li, Z., Cui, K., Ding, J., Kohandehghan, A., Tan, X., Zahiri, B., Olsen, B. C., Holt, C. M. B., & Mitlin, D. (2014). Hybrid Device Employing Three-Dimensional Arrays of MnO in Carbon Nanosheets Bridges Battery–Supercapacitor Divide. Nano Letters. https://doi.org/10.1021/nl500011d
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