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Investigation Regarding the Role of Chloride in Organic–Inorganic Halide Perovskites Obtained from Chloride Containing Precursors
Open accessAbstract
As the photovoltaic performance of a device is strongly influenced by the morphology of perovskite, achieving precise control over the crystal formation of organic-inorganic halide perovskites synthesized in the ambience of chloride ions has garnered much attention. Although the resulting morphology dictates the performance of the device considerably, the understanding of the role of chloride ions has been scant. To unravel this mystery, we investigated three different organic-inorganic halide perovskite materials grown from the chloride-containing precursors under different but optimized conditions. Despite the presence of chloride ions in the reaction mixture, scanning transmission electron microscopy- energy dispersive spectroscopy (STEM-EDS) reveals that the CH3NH3PbI3 perovskites formed are chloride-free. Moreover bright field transmission electron microscopy indicates that chloride ions effect the growth of the CH3NH3PbI3.
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Cites
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
Jeon, N. J., Noh, J. H., Kim, Y. C., Yang, W. S., Ryu, S., & Seok, S. I. (2014) · Nature Materials · doi:10.1038/nmat4014 · Cited by 6,723
Cited by
Metal-halide perovskites for photovoltaic and light-emitting devices
Stranks, S. D., & Snaith, H. J. (2015) · Nature Nanotechnology · doi:10.1038/nnano.2015.90 · Cited by 3,392
Under the spotlight: The organic–inorganic hybrid halide perovskite for optoelectronic applications
Chen, Q., De Marco, N., Yang, Y. (., Song, T.-B., Chen, C.-C., Zhao, H., Hong, Z., Zhou, H., & Yang, Y. (2015) · Nano Today · doi:10.1016/j.nantod.2015.04.009 · Cited by 1,154
Trap States in Lead Iodide Perovskites
Wu, X., Trinh, M. T., Niesner, D., Zhu, H., Norman, Z., Owen, J. S., Yaffe, O., Kudisch, B. J., & Zhu, X.-Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja512833n · Cited by 988
Charge-Carrier Dynamics in Organic-Inorganic Metal Halide Perovskites
Herz, L. M. (2016) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-040215-112222 · Cited by 819
Causes and Solutions of Recombination in Perovskite Solar Cells
Chen, J., & Park, N. (2019) · Advanced Materials · doi:10.1002/adma.201803019 · Cited by 733
Metadata
- Authors
- Dar, M. I., Arora, N., Gao, P., Ahmad, S., Grätzel, M., & Nazeeruddin, M. K.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-11-20
- Volume
- 14
- Issue
- 12
- Pages
- 6991-6996
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2068257829
- Cited by
- 193
- References
- 1
- FWCI
- 19.10
- Type
- journal article
- Language
- en
- Open access
- green
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