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Polymer Nanofiber-Guided Uniform Lithium Deposition for Battery Electrodes

Liang, Zheng, Zheng, Guangyuan, Liu, Chong, Liu, Nian, Li, Weiyang, Yan, Kai, Yao, Hongbin, Hsu, Po-Chun, Chu, Steven, Cui, Yi·2015·Nano Letters

Abstract

Lithium metal is one of the most promising candidates as an anode material for next-generation energy storage systems due to its highest specific capacity (3860 mAh/g) and lowest redox potential of all. The uncontrolled lithium dendrite growth that causes a poor cycling performance and serious safety hazards, however, presents a significant challenge for the realization of lithium metal-based batteries. Here, we demonstrate a novel electrode design by placing a three-dimensional (3D) oxidized polyacrylonitrile nanofiber network on top of the current collector. The polymer fiber with polar surface functional groups could guide the lithium ions to form uniform lithium metal deposits confined on the polymer fiber surface and in the 3D polymer layer. We showed stable cycling of lithium metal anode with an average Coulombic efficiency of 97.4% over 120 cycles in ether-based electrolyte at a current density of 3 mA/cm(2) for a total of 1 mAh/cm(2) of lithium.

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Metadata

Authors
Liang, Z., Zheng, G., Liu, C., Liu, N., Li, W., Yan, K., Yao, H., Hsu, P.-C., Chu, S., & Cui, Y.
Venue
Nano Letters
Published
2015-04-09
Volume
15
Issue
5
Pages
2910-2916
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2313044201
Cited by
540
References
0
FWCI
26.78
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Polymer Nanofiber-Guided Uniform Lithium Deposition for Battery Electrodes. https://app.cochat.ai/papers/10.1021/nl5046318
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Liang, Z., Zheng, G., Liu, C., Liu, N., Li, W., Yan, K., Yao, H., Hsu, P.-C., Chu, S., & Cui, Y. (2015). Polymer Nanofiber-Guided Uniform Lithium Deposition for Battery Electrodes. Nano Letters. https://doi.org/10.1021/nl5046318

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