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Electronic Structure of Few-Layer Epitaxial Graphene on Ru(0001)
Abstract
The electronic structure of epitaxial monolayer, bilayer, and trilayer graphene on Ru(0001) was determined by selected-area angle-resolved photoelectron spectroscopy (micro-ARPES). Micro-ARPES band maps provide evidence for a strong electronic coupling between monolayer graphene and the adjacent metal, which causes the complete disruption of the graphene pi-bands near the Fermi energy. However, the perturbation by the metal decreases rapidly with the addition of further graphene sheets, and already an epitaxial graphene bilayer on Ru recovers the characteristic Dirac cones of isolated monolayer graphene. A graphene trilayer on Ru behaves like free-standing bilayer graphene. Density-functional theory based calculations show that this decoupling is due to the efficient passivation of metal d-states by the interfacial graphene layer.
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Cites
Self-interaction correction to density-functional approximations for many-electron systems
Perdew, J. P., & Zunger, A. (1981) · Physical Review B · doi:10.1103/physrevb.23.5048 · Cited by 20,887
Cited by
A review of chemical vapour deposition of graphene on copper
Mattevi, C., Kim, H., & Chhowalla, M. (2011) · J. Mater. Chem. · doi:10.1039/c0jm02126a · Cited by 1,452
Van der Waals heterostructures
Castellanos-Gomez, A., Duan, X., Fei, Z., Gutierrez, H. R., Huang, Y., Huang, X., Quereda, J., Qian, Q., Sutter, E., & Sutter, P. (2022) · Nature Reviews Methods Primers · doi:10.1038/s43586-022-00139-1 · Cited by 423
Self-citationGraphene Chemistry: Synthesis and Manipulation
Sun, Z., James, D. K., & Tour, J. M. (2011) · The Journal of Physical Chemistry Letters · doi:10.1021/jz201000a · Cited by 259
Metadata
- Authors
- Sutter, P., Hybertsen, M. S., Sadowski, J. T., & Sutter, E.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-06-08
- Volume
- 9
- Issue
- 7
- Pages
- 2654-2660
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2055413753
- Cited by
- 238
- References
- 1
- FWCI
- 10.69
- Type
- journal article
- Language
- en
- Open access
- closed
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