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Ordered Mesoporous Metallic MoO2 Materials with Highly Reversible Lithium Storage Capacity
Abstract
Highly ordered mesoporous crystalline MoO(2) materials with bicontinuous Ia3d mesostructure were synthesized by using phosphomolybdic acid as a precursor and mesoporous silica KIT-6 as a hard template in a 10% H(2) atmosphere via nanocasting strategy. The prepared mesoporous MoO(2) material shows a typical metallic conductivity with a low resistivity ( approximately 0.01Omega cm at 300 K), which makes it different from all previously reported mesoporous metal oxides materials. Primary test found that mesoporous MoO(2) material exhibits a reversible electrochemical lithium storage capacity as high as 750 mA h g(-1) at C/20 after 30 cycles, rendering it as a promising anode material for lithium ion batteries.
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Citations
Cites
Generalized syntheses of large-pore mesoporous metal oxides with semicrystalline frameworks
Yang, P., Zhao, D., Margolese, D. I., Chmelka, B. F., & Stucky, G. D. (1998) · Nature · doi:10.1038/24132 · Cited by 2,493
Self-citationElectrically conductive oxide aerogels: new materials in electrochemistry
Rolison, D. R., & Dunn, B. (2001) · Journal of Materials Chemistry · doi:10.1039/b007591o · Cited by 357
Cited by
Cabana, J., Monconduit, L., Larcher, D., & Palacín, M. R. (2010) · Advanced Materials · doi:10.1002/adma.201000717 · Cited by 2,361
Transition Metal Oxides for Organic Electronics: Energetics, Device Physics and Applications
Meyer, J., Hamwi, S., Kröger, M., Kowalsky, W., Riedl, T., & Kahn, A. (2012) · Advanced Materials · doi:10.1002/adma.201201630 · Cited by 1,248
Chen, Z., Cummins, D., Reinecke, B. N., Clark, E., Sunkara, M. K., & Jaramillo, T. F. (2011) · Nano Letters · doi:10.1021/nl2020476 · Cited by 1,153
Porous MoO2 Nanosheets as Non‐noble Bifunctional Electrocatalysts for Overall Water Splitting
Jin, Y., Wang, H., Li, J., Yue, X., Han, Y., Shen, P. K., & Cui, Y. (2016) · Advanced Materials · doi:10.1002/adma.201506314 · Cited by 803
Porous electrode materials for lithium-ion batteries–how to prepare them and what makes them special
Vu, A., Qian, Y., & Stein, A. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201200320 · Cited by 719
Metadata
- Authors
- Shi, Y., Guo, B., Corr, S. A., Shi, Q., Hu, Y.-S., Heier, K. R., Chen, L., Seshadri, R., & Stucky, G. D.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-09-23
- Volume
- 9
- Issue
- 12
- Pages
- 4215-4220
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2060315855
- Cited by
- 683
- References
- 2
- FWCI
- 28.51
- Type
- journal article
- Language
- en
- Open access
- closed
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